Progress in the Synthesis and Transformations of Alkylidenecyclopropanes and Alkylidenecyclobutanes

A Brandi, S Cicchi, FM Cordero, A Goti - Chemical Reviews, 2014 - ACS Publications
Methylene-and alkylidenecyclopropanes (MCPs and ACPs, 1, Figure 1) and-cyclobutanes
(MCBs and ACBs, 2, Figure 1) are highly strained molecules, but at the same time most of …

Heterocycles from alkylidenecyclopropanes

A Brandi, S Cicchi, FM Cordero, A Goti - Chemical reviews, 2003 - ACS Publications
Heterocyclic compounds, which represent almost two-thirds of all the known organic
compounds, include some of the most significant for human beings. It is not surprising …

Cyclopropenes and methylenecylopropanes as multifunctional reagents in transition metal catalyzed reactions

P Binger, HM Büch - Small Ring Compounds in Organic Synthesis II, 2005 - Springer
The tremendous potential of cyclopropenes and methylene-cyclopropanes as
multifunctional reagents in organic syntheses has only been recognized in the last decade …

Trimethylamine N-oxide—A versatile reagent for organometallic chemistry

TY Luh - Coordination chemistry reviews, 1984 - Elsevier
The organic chemistry of amine N-oxides is rich [l-4]. Numerous examples illustrate that this
type of compound can serve as an oxidant in organic and organometallic chemistry, and as …

[图书][B] Pericyclic Reactions-A Textbook: Reactions, Applications and Theory

S Sankararaman - 2005 - books.google.com
Based on twelve years of teaching a graduate course, this long awaited textbook presents
Diels-Alder reactions, electrocyclic reactions, sigmatropic rearrangements plus many more …

Ruthenium‐Catalyzed Hydroarylation of Methylenecyclopropanes through C H Bond Cleavage: Scope and Mechanism

L Ackermann, SI Kozhushkov… - Chemistry–A European …, 2012 - Wiley Online Library
Intermolecular hydroarylation reactions of highly strained methylenecyclopropanes 2‐
phenylmethylenecyclopropane (1), 2, 2‐diphenylmethylenecyclopropane (2) …

Hydrogen-transfer reactions which generate new imine, imido, and trimethylenemethane complexes of tantalum

JM Mayer, CJ Curtis, JE Bercaw - Journal of the American …, 1983 - ACS Publications
The reactions of Cp* TaMe3Cl (Cp*= rj5 678-C5Me5) with a variety of alkali-metal alkoxide,
alkylamide, and alkyl reagents have been examined. Reaction with LiNMe2 produces Cp …

Transition metal catalyzed stereospecific intramolecular [3+ 2] cycloadditions of methylenecyclopropanes with alkynes

M Lautens, Y Ren - Journal of the American Chemical Society, 1996 - ACS Publications
Palladium catalyzed intramolecular [3+ 2] cycloadditions of diastereomerically pure
methylenecyclopropanes MCPs have been investigated. The reaction was found to be …

[PDF][PDF] Bonding of unsaturated organic molecules to transition metals

DMP Mingos - Comprehensive organometallic chemistry, 1982 - academia.edu
The rapid development of organometallic chemistry following the discovery of ferrocene in
the early 1950s resulted in the isolation of a wide variety of compounds with unusual and at …

Bromine–magnesium exchange in gem-dibromocyclopropanes using Grignard reagents

MS Baird, AV Nizovtsev, IG Bolesov - Tetrahedron, 2002 - Elsevier
Reaction of gem-dibromocyclopropanes with ethylmagnesium bromide at ambient
temperature leads to very high yields of allenes; when cyclopropylidene–allene ring …