The development of sufficiently effective catalysts with extremely superior performance for
electrocatalytic hydrogen production still remains a formidable challenge, especially in …

Metal-based heterogeneous catalysts mostly consist of supported nanoparticles of a few
nanometers in size, since these objects provide a good compromise between exposed …

In the past decades, complex hydrides and complex hydrides-based materials have been
thoroughly investigated as materials for energy storage, owing to their very high gravimetric …

The superior hydrogenation of carbonyl (C= O) bonds in α, β-unsaturated aldehydes (UAL)
has attracted considerable attention from economic and industrial perspectives. Several …

Abstract High‐entropy‐alloy (HEA) nanocrystals hold immense potential for catalysis,
offering virtually unlimited alloy combinations through the inclusion of at least five constituent …

We report an experimental study, supported by a theoretical approach based on simulations,
to explore the phenomenon of H trapping in small Pd nanoparticles. Hydrogen …

Operando probing by x‐ray photoelectron spectroscopy (XPS) of certain hydrogenation
reactions are often limited by the scattering of photoelectrons in the gas phase. This work …

Rh-hydride phases were believed to be key causes of the exceptional catalytic ability of Rh
catalysts under H2 reductive conditions. Here, we utilize the large-scale machine-learning …

Physisorption and chemisorption of hydrogen on solid‐state materials are two fundamentally
different interactions, both of which display advantages and drawbacks for hydrogen …

Subsurface H can affect catalytic reactivity and selectivity. H resurface and H2 recombination
with a subsurface H on Ni (111) were investigated by the quantum instanton method, and …