The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Bismuth has recently been shown to be able to maneuver between different oxidation states,
enabling access to unique redox cycles that can be harnessed in the context of organic …

Herein, we report a Ni-catalyzed C (sp2)–H hydroxylation of aryl bromides with N2O as an
oxygen-atom donor. The reaction is enabled by a 1, 4-Ni translocation that results in …

Herein we present the catalytic activation of N2O at a BiI⇄ BiIII redox platform. The activation
of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts …

The Co (− I) dihydrogen complexes,[(η2-H2) CoML]−, where ML is the group 13
metalloligand, N (o-(NCH2PiPr2) C6H4) 3M, and M is Al, Ga, or In, were previously reported …

Herein, we report the efficient degradation of N2O with a well‐defined bis (silylene) amido
iron complex as catalyst. The deoxygenation of N2O using the iron silanone complex 4 as a …

Due to its significant contribution to stratospheric ozone depletion and its potent greenhouse
effect, nitrous oxide has stimulated much research interest regarding its reactivity modes and …

Tertiary phosphines (III) find widespread use in many aspects of synthetic organic chemistry.
Herein, we developed a facile and novel electrochemical oxidative N–H/P–H cross-coupling …

Both CO and N2O are important, environmentally harmful industrial gases. The reaction of
CO and N2O to produce CO2 and N2 has stimulated much research interest aimed at …

The hydrogenation of nitrous oxide by PNP pincer ruthenium complexes supposes a
promising way to functionalize a hazardous gas and reduce the greenhouse effect …