Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Engineering luminescent metal nanoclusters for sensing applications

S Qian, Z Wang, Z Zuo, X Wang, Q Wang… - Coordination Chemistry …, 2022 - Elsevier
Metal nanoclusters (MNCs) have ultrasmall size (≤ 3 nm), precise molecular structure,
strong luminescence, size-sensitive physicochemical properties, engineerable metallic …

Alkynyl-stabilized superatomic silver clusters showing circularly polarized luminescence

MM Zhang, XY Dong, ZY Wang, XM Luo… - Journal of the …, 2021 - ACS Publications
We report a new enantiomeric pair of superatomic silver clusters, R/S-Ag 17, prepared from
chiral alkynyl ligands. R-Ag 17 and S-Ag 17 possess C 3 symmetry and emit near-infrared …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Correlations between the fundamentals and applications of ultrasmall metal nanoclusters: Recent advances in catalysis and biomedical applications

Z Liu, Z Wu, Q Yao, Y Cao, OJH Chai, J Xie - Nano Today, 2021 - Elsevier
Ultrasmall metal nanoparticles (NPs) with a well-defined composition and structure, the so-
called metal nanoclusters (NCs, usually smaller than 3 nm in size), represent the forefront …

Stereospecific interactions between chiral inorganic nanomaterials and biological systems

X Zhao, SQ Zang, X Chen - Chemical Society Reviews, 2020 - pubs.rsc.org
Chirality is ubiquitous in nature and plays mysterious and essential roles in maintaining key
biological and physiological processes. As biological systems display high selectivity for …

Chirality and surface bonding correlation in atomically precise metal nanoclusters

Y Li, T Higaki, X Du, R Jin - Advanced Materials, 2020 - Wiley Online Library
Chirality is ubiquitous in nature and occurs at all length scales. The development of
applications for chiral nanostructures is rising rapidly. With the recent achievements of …

Identifying Highly Photoelectrochemical Active Sites of Two Au21 Nanocluster Isomers toward Bright Near-Infrared Electrochemiluminescence

M Hesari, Z Ding - Journal of the American Chemical Society, 2021 - ACS Publications
Thus far, no correlation between nanocluster structures and their electrochemiluminescence
(ECL) has been identified. Herein, we report how face-centered-cubic and hexagonal close …

Revealing the chirality origin and homochirality crystallization of Ag14 nanocluster at the molecular level

XQ Liang, YZ Li, Z Wang, SS Zhang, YC Liu… - Nature …, 2021 - nature.com
Although chirality is an ever-present characteristic in biology and some artificial molecules,
controlling the chirality and demystifying the chirality origin of complex assemblies remain …

Vibrational properties of thiolate-protected gold nanoclusters

B Nieto-Ortega, T Burgi - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Over recent years, the field of thiolate-protected gold nanoclusters has made
remarkable progress. The successful determination of the structure of some of these clusters …