Recent advances in selective mono-/dichalcogenation and exclusive dichalcogenation of C (sp 2)–H and C (sp 3)–H bonds

CS Wang, Y Xu, SP Wang, CL Zheng… - Organic & Biomolecular …, 2024 - pubs.rsc.org
Organochalcogen compounds are prevalent in numerous natural products,
pharmaceuticals, agrochemicals, polymers, biological molecules and synthetic …

From ketones to esters by a Cu-catalyzed highly selective C (CO)–C (alkyl) bond cleavage: aerobic oxidation and oxygenation with air

X Huang, X Li, M Zou, S Song, C Tang… - Journal of the …, 2014 - ACS Publications
The Cu-catalyzed aerobic oxidative esterification of simple ketones via C–C bond cleavage
has been developed. Varieties of common ketones, even inactive aryl long-chain alkyl …

Factors That Control C–C Cleavage versus C–H Bond Hydroxylation in Copper-Catalyzed Oxidations of Ketones with O2

ASK Tsang, A Kapat… - Journal of the American …, 2016 - ACS Publications
The Cu-catalyzed oxidation of ketones with O2 has recently been extensively utilized to
cleave the α-C–C bond. This report examines the selective aerobic hydroxylation of tertiary α …

Assessing Methodologies to Synthesize α‐Sulfenylated Carbonyl Compounds by Green Chemistry Metrics

J Margalef, JSM Samec - ChemSusChem, 2021 - Wiley Online Library
Abstract α‐Sulfenylated carbonyl compounds are important both as active pharmaceutical
ingredients and as intermediates in organic synthesis. Owing to their relevance in synthetic …

Iodine-Mediated Thiolation of Substituted Naphthols/Naphthylamines and Arylsulfonyl Hydrazides via C(sp2)–H Bond Functionalization

X Kang, R Yan, G Yu, X Pang, X Liu, X Li… - The Journal of …, 2014 - ACS Publications
A direct method has been developed for iodine-mediated thiolation of naphthols/
naphthylamines and arylsulfonyl hydrazides through the formation of C–S bond and …

Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides

S Guo, W He, J Xiang, Y Yuan - Chemical Communications, 2014 - pubs.rsc.org
A new method for the preparation of alkyl aryl sulfides through direct oxidative thiolation of
alkanes or ethers with arylsulfonyl hydrazides using di-tert-butyl peroxide (DTBP) as an …

Copper-catalyzed three-component annulation toward pyrroles via the cleavage of two C–C bonds in 1, 3-dicarbonyls

G Xu, L Li, B Xu, Z Fang, J Duan, K Guo - Chemical Communications, 2023 - pubs.rsc.org
The first copper-catalyzed three-component annulation of α, β-unsaturated ketoximes, 1, 3-
dicarbonyls and paraformaldehyde has been documented. This novel strategy achieved the …

Ruthenium (ii)-catalyzed chemoselective deacylative annulation of 1, 3-diones with sulfoxonium ylides via C–C bond activation

S Wen, W Lv, D Ba, J Liu, G Cheng - Chemical Science, 2019 - pubs.rsc.org
The first successful example of deacylative annulation of 1, 3-diones with sulfoxonium ylides
was achieved through Ru (II)-catalyzed C–C bond activation. The excellent chemoselectivity …

Metal-free iodine-catalyzed synthesis of fully substituted pyrazoles and its sulphenylation

J Sun, JK Qiu, YL Zhu, C Guo, WJ Hao… - The Journal of …, 2015 - ACS Publications
A direct and metal-free access toward fully substituted pyrazoles and its sulphenylation has
been established through an iodine-mediated three-component [3+ 2] annulation of β …

Silver‐Catalyzed Oxidative C(sp3)−P Bond Formation through C−C and P−H Bond Cleavage

L Li, W Huang, L Chen, J Dong, X Ma… - Angewandte …, 2017 - Wiley Online Library
The silver‐catalyzed oxidative C (sp3)− H/P− H cross‐coupling of 1, 3‐dicarbonyl
compounds with H‐phosphonates, followed by a chemo‐and regioselective C (sp3)− C (CO) …