Chemistry, Physical Chemistry, and Uses of Molecular Fluorocarbon− Hydrocarbon Diblocks, Triblocks, and Related Compounds Unique “Apolar” Components for …

MP Krafft, JG Riess - Chemical reviews, 2009 - ACS Publications
The semifluorinated molecular diblock compounds considered here consist primarily of
covalent assemblages of a linear perfluoroalkyl chain (F-chain, CnF2n+ 1) and a linear …

Cyclic bis‐urea compounds as gelators for organic solvents

JH van Esch, F Schoonbeek, M de Loos… - … A European Journal, 1999 - Wiley Online Library
Self‐assembly of cyclic bis‐urea compounds takes place even at low concentrations to form
very thin fibers which give a three‐dimensional network in the solvent. The X‐ray structure …

Synthesis and surface properties of environmentally responsive segmented polyurethanes

A Vaidya, MK Chaudhury - Journal of Colloid and Interface Science, 2002 - Elsevier
Polyurethanes, containing well-defined assemblies of perfluoro-polyether (PFPE or
hexafluoropropene oxide oligomer), polydimethylsiloxane (PDMS), and polyethylene glycol …

Dramatic stabilization of a hexagonal columnar mesophase generated from supramolecular and macromolecular columns by the semifluorination of the alkyl groups …

V Percec, D Schlueter, YK Kwon, J Blackwell… - …, 1995 - ACS Publications
In a series of publications from our laboratory we have reported on the self-assembly of
tapered building blocks containing various endo-receptorssuch as crown ethers, oligo …

Surface activity of semifluorinated alkanes: F (CF2) m (CH2) nH

GL Gaines Jr - Langmuir, 1991 - ACS Publications
The surface tensions of dilute dodecane solutions of several semifluorinated alkanes have
been measured at room temperature. Decrements of up to 4 mN/m have been observed …

Aggregation of amphiphilic molecules in supercritical carbon dioxide: a small angle X-ray scattering study

JL Fulton, DM Pfund, JB McClain, TJ Romack… - Langmuir, 1995 - ACS Publications
Highly soluble amphiphilic materials are shown to form aggregates insupercritical CO2. The
strategy for synthesis of these amphiphilic molecules involves incorporating CfVphilic …

Molecular engineering of liquid crystal polymers by living polymerization. XXIII. Synthesis and characterization of AB block copolymers based on ω-[(4-cyano-4 …

V Percec, M Lee - Journal of Macromolecular Science—Pure and …, 1992 - Taylor & Francis
This paper describes the synthesis and characterization of AB block copolymers based on ω-
[(4-cyano-4′-biphenyl) oxy] alkyl vinyl ether (6-n), with alkyl being ethyl (6-2), propyl (6-3) …

On the morphology of (perfluoroalkyl) alkanes

J Hopken, M Moller - Macromolecules, 1992 - ACS Publications
The melting and crystallization behavior of (perfluorododecyl) eicosane, F (CF2) i2 (CH2)
2oH, has been investigated by DSC, MAS 13C NMR, and electron microscopic studies. A …

Adsorption and aggregation of semifluorinated alkanes in binary and ternary mixtures with hydrocarbon and fluorocarbon solvents

BP Binks, PDI Fletcher, SN Kotsev, RL Thompson - Langmuir, 1997 - ACS Publications
The phase behavior, adsorption, and aggregation of semifluorinated alkanes (SFAs) of
general structure F (CF2) n (CH2) m H (abbreviated to F n H m) in hydrocarbon and …

'Gel'formation in carbon dioxide-semifluorinated alkane mixtures and phase equilibria of a carbon dioxide-perfluorinated alkane mixture

A Iezzi, P Bendale, RM Enick, M Turberg, J Brady - Fluid Phase Equilibria, 1989 - Elsevier
A 'gel'has been observed in mixtures of dense carbon dioxide and semifluorinated alkanes.
This gelation occurred when a liquid-vapor binary solution was isothermally expanded at …