Porous organic cages

X Yang, Z Ullah, JF Stoddart, CT Yavuz - Chemical Reviews, 2023 - ACS Publications
Porous organic cages (POCs) are a relatively new class of low-density crystalline materials
that have emerged as a versatile platform for investigating molecular recognition, gas …

Adaptive catalytic systems for chemical energy conversion

A Bordet, W Leitner - Angewandte Chemie International Edition, 2023 - Wiley Online Library
The rapidly growing importance of green hydrogen and renewable carbon resources as
essential feedstocks for sustainable chemical value chains opens room for disruptive …

Sub-8 nm networked cage nanofilm with tunable nanofluidic channels for adaptive sieving

SH Liu, JH Zhou, C Wu, P Zhang, X Cao… - Nature …, 2024 - nature.com
Biological cell membrane featuring smart mass-transport channels and sub-10 nm thickness
was viewed as the benchmark inspiring the design of separation membranes; however …

New liquid chemical hydrogen storage technology

X Yang, DA Bulushev, J Yang, Q Zhang - Energies, 2022 - mdpi.com
The liquid chemical hydrogen storage technology has great potentials for high-density
hydrogen storage and transportation at ambient temperature and pressure. However, its …

Dynamic Cages—Towards Nanostructured Smart Materials

W Drożdż, A Ciesielski… - Angewandte Chemie, 2023 - Wiley Online Library
The interest in capsular assemblies such as dynamic organic and coordination cages has
blossomed over the last decade. Given their chemical and structural variability, these …

Air‐Stable Radical Organic Cages as Cascade Nanozymes for Enhanced Catalysis

XD Yang, YJ Zhang, JH Zhou, L Liu, JK Sun - Small, 2023 - Wiley Online Library
The pursuit of single‐assembled molecular cage reactors for complex tandem reactions is a
long‐standing target in biomimetic catalysis but still a grand challenge. Herein, nanozyme …

Cooperative cage hybrids enabled by electrostatic marriage

L Zhu, X Yang, JK Sun - Chemical Communications, 2023 - pubs.rsc.org
A cage hybrid (C-Cage–PB) was developed by electrostatic complexation of a quaternary
ammonium cage (C-Cage+) and an anionic inorganic Prussian blue (PB−). Given the …

Encapsulation of metal clusters within porous organic materials: from synthesis to catalysis applications

XD Yang, L Tan, JK Sun - Chemistry–An Asian Journal, 2022 - Wiley Online Library
Metal clusters (MCs) with dimensions between a single metal atom and nanoparticles of> 2
nm usually possess distinct geometric and electronic structures, and their outstanding …

The marriage of porous cages and metal clusters for advanced catalysis

JY Li, XD Yang, FX Chen, JK Sun - Materials Chemistry Frontiers, 2023 - pubs.rsc.org
Metal clusters (MCs), a special species of ultrafine metal nanoparticles with dimensions
below 2 nm, serve as highly active catalysts for a broad spectrum of chemical reactions, but …

Recent advances in porous molecular cages for photocatalytic organic conversions

Y Peng, Z Su, M Jin, L Zhu, ZJ Guan, Y Fang - Dalton Transactions, 2023 - pubs.rsc.org
Photocatalytic organic conversion is considered an efficient, environmentally friendly, and
energy-saving strategy for organic synthesis. In recent decades, the molecular cage has …