While β-diketiminate (BDI or 'nacnac') ligands have been widely adopted to stabilize a wide
range of metal ions in multiple oxidation states and coordination numbers, in several …

This review gives an overview of the progress on tri-and high-nuclearity palladium (II)
platinum (II) complexes and discusses recent developments in the chemistry of these …

Metal–ligand cooperative systems have a long precedent in catalysis, with the classification
depending on the site of substrate bond cleavage and formation and on redox state …

The reaction between (Ar2nacnac) H (Ar= C6H5, ligand a; 2, 6-(i Pr) 2C6H3, ligand b) and
[Pd (OAc) 2] produces red complexes [Pd (Ar2nacnac)(OAc)](1a: Ar= C6H5; 1b: Ar= 2, 6-(i …

The reaction of 4, 5-diazafluorene (LH) and NaH generates NaL, which reacts with Pd
(PPh3) 2Cl2 and [Rh (COD) Cl] 2 to afford [Pd (PPh3) ClL] 2 (1) and Rh (COD) L (2) …

Palladium (II) complexes with a bidentate, anionic formazanate ligand are described.
Attempts to prepare mono (formazanate) palladium alkyl complexes often leads to the …

Here we report the synthesis and characterization of a series of palladium β-diiminate
complexes. Chloro-bridged dimers [Pd (Ar2nacnac)(μ-Cl)] 2 (where [Ar2nacnac]− is [(ArNC …

The most common β-diketiminate ligand,[{N (2, 6-i Pr2C6H3) C (Me)} 2CH]−(BDI), was used
to synthesize a new mercury complex in which two BDI ligands are bound to the metal …

A series of crystalline late transition metal β-diketiminates 1–10, using the ligand [{N (SiMe3)
C (Ph)} 2CH]−(≡ L−) or [{N (H) C (Ph)} 2CH]−(≡ L′−) is reported. The homoleptic pseudo …

Unusual transmetallation -induced formation of a C 2 -symmetric tetrapallada - macrocycle -
Chemical Communications (RSC Publishing) DOI:10.1039/C0CC03314F Royal Society of …