Bio-sourced monomers and cationic photopolymerization–The green combination towards eco-friendly and non-toxic materials

L Pierau, C Elian, J Akimoto, Y Ito, S Caillol… - Progress in Polymer …, 2022 - Elsevier
Cationic photopolymerization is amongst the greenest processes used to obtain polymers
since light is abundant, inexpensive and allows for rapid and waste-less curing at room …

Role of external field in polymerization: mechanism and kinetics

YN Zhou, JJ Li, YY Wu, ZH Luo - Chemical reviews, 2020 - ACS Publications
The past decades have witnessed an increasing interest in developing advanced
polymerization techniques subjected to external fields. Various physical modulations, such …

Development of a platform for near-infrared photoredox catalysis

BD Ravetz, NES Tay, CL Joe… - ACS central …, 2020 - ACS Publications
Over the past decade, chemists have embraced visible-light photoredox catalysis due to its
remarkable ability to activate small molecules. Broadly, these methods employ metal …

Carbon dots as a promising green photocatalyst for free radical and ATRP‐based radical photopolymerization with blue LEDs

C Kütahya, P Wang, S Li, S Liu, J Li… - Angewandte Chemie …, 2020 - Wiley Online Library
Carbon dots (CDs) have been used for the first time as a sensitizer to initiate and activate
free radical and controlled radical polymerization, respectively, based on an ATRP protocol …

Tris‐benzo[cd]indole Cyanine Enables the NIR‐photosensitized Radical and Thiol‐ene Polymerizations at 940 nm

C Elian, B Mourot, C Benbouziyane… - Angewandte Chemie …, 2023 - Wiley Online Library
A near‐infrared‐absorbing heptamethine (HM+) incorporating three bulky benzo [cd] indole
heterocycles was designed to efficiently prevent self‐aggregation of the dye, which results in …

Effective Utilization of NIR Wavelengths for Photo‐Controlled Polymerization: Penetration Through Thick Barriers and Parallel Solar Syntheses

Z Wu, K Jung, C Boyer - Angewandte Chemie International …, 2020 - Wiley Online Library
This contribution details an efficient and controlled photopolymerization regulated by far‐red
(λ= 680 nm) and NIR (λ= 780 and 850 nm) light in the presence of aluminium …

Design of photoinitiating systems based on the chalcone-anthracene scaffold for LED cationic photopolymerization and application in 3D printing

S Liu, Y Zhang, K Sun, B Graff, P Xiao, F Dumur… - European Polymer …, 2021 - Elsevier
In this study, light-emitting diodes (LEDs) used as secure, low-cost and possessing long
emission wavelengths irradiation sources were applied in photopolymerization. Seven novel …

Nitro‐Carbazole Based Oxime Esters as Dual Photo/Thermal Initiators for 3D Printing and Composite Preparation

S Liu, B Graff, P Xiao, F Dumur… - Macromolecular Rapid …, 2021 - Wiley Online Library
A series of Type I photoinitiators (PIs) based on a nitrocarbazole scaffold are developed and
examined for the first time as photoinitiators for visible light photopolymerization. Three …

Catalyst halogenation enables rapid and efficient polymerizations with visible to far-red light

A Stafford, D Ahn, EK Raulerson… - Journal of the …, 2020 - ACS Publications
The driving of rapid polymerizations with visible to near-infrared light will enable nascent
technologies in the emerging fields of bio-and composite-printing. However, current …

New multifunctional benzophenone-based photoinitiators with high migration stability and their applications in 3D printing

S Liu, D Brunel, G Noirbent, A Mau, H Chen… - Materials Chemistry …, 2021 - pubs.rsc.org
In this paper, seven new photoinitiators based on the benzophenone scaffold are
specifically designed for photopolymerization under mild conditions upon light-emitting …