The merger of photoredox and cobalt catalysis

M Kojima, S Matsunaga - Trends in Chemistry, 2020 - cell.com
In the past decade, synthetic chemists have discovered the outstanding generality and
potential of visible-light-driven photoredox catalysis, which converts visible light into …

Biomimetic Photoexcited Cobaloxime Catalysis in Organic Synthesis

P Dam, K Zuo, LM Azofra, O El‐Sepelgy - Angewandte Chemie, 2024 - Wiley Online Library
Drawing inspiration from nature has long been a cornerstone of chemical innovation, with
natural systems offering a wealth of untapped potential for discovery. In this minireview, we …

Switchable divergent synthesis using photocatalysis

Y Sakakibara, K Murakami - ACS Catalysis, 2022 - ACS Publications
A highly selective and divergent synthesis enables access to various molecules and has
garnered broad interest from not only organic chemists but also medicinal chemists and …

Integrating Hydrogen Production with Aqueous Selective Semi‐Dehydrogenation of Tetrahydroisoquinolines over a Ni2P Bifunctional Electrode

C Huang, Y Huang, C Liu, Y Yu… - Angewandte Chemie, 2019 - Wiley Online Library
Exploring an alternative anodic reaction to produce value‐added chemicals with high
selectivity, especially integrated with promoted hydrogen generation, is desirable. Herein, a …

Sensitizer-controlled photochemical reactivity via upconversion of red light

F Glaser, OS Wenger - Chemical Science, 2023 - pubs.rsc.org
By combining the energy input from two red photons, chemical reactions that would normally
require blue or ultraviolet irradiation become accessible. Key advantages of this biphotonic …

Advancement in photocatalytic acceptorless dehydrogenation reactions: Opportunity and challenges for sustainable catalysis

PK Verma - Coordination Chemistry Reviews, 2022 - Elsevier
Dehydrogenation reactions are the challenging and thermodynamically unfavorable.
Traditionally, high temperature and pressure conditions, excess of oxidants and sacrificial …

Asymmetric C–H dehydrogenative allylic alkylation by ternary photoredox-cobalt-chiral primary amine catalysis under visible light

Z Jia, L Zhang, S Luo - Journal of the American Chemical Society, 2022 - ACS Publications
We report herein an asymmetric C–H dehydrogenative allylic alkylation by a synergistic
catalytic system involving a chiral primary amine, a photoredox catalyst, and a cobaloxime …

Direct Arylation of α‐Amino C(sp3)‐H Bonds by Convergent Paired Electrolysis

Y Ma, X Yao, L Zhang, P Ni… - Angewandte Chemie …, 2019 - Wiley Online Library
A metal‐free convergent paired electrolysis strategy to synthesize benzylic amines through
direct arylation of tertiary amines and benzonitrile derivatives at room temperature has been …

Rh/TiO2-Photocatalyzed Acceptorless Dehydrogenation of N-Heterocycles upon Visible-Light Illumination

NO Balayeva, Z Mamiyev, R Dillert, N Zheng… - ACS …, 2020 - ACS Publications
TiO2 is an effective and extensively employed photocatalyst, but its practical use in visible-
light-mediated organic synthesis is mainly hindered by its wide band gap energy. Herein, we …

Cobaloxime Photocatalysis for the Synthesis of Phosphorylated Heteroaromatics

JX Yu, YY Cheng, B Chen, CH Tung… - Angewandte Chemie …, 2022 - Wiley Online Library
Herein, cobaloxime is used for the first time as a catalyst for the synthesis of phosphorylated
heteroaromatics, which is an intriguing and versatile functional motif. With visible‐light …