The mononuclear molybdenum enzymes

R Hille, J Hall, P Basu - Chemical reviews, 2014 - ACS Publications
Molybdenum is the only second-row transition metal required by most living organisms, and
is nearly universally distributed in biology. Enzymes containing molybdenum in their active …

Microbial degradation of aromatic compounds—from one strategy to four

G Fuchs, M Boll, J Heider - Nature Reviews Microbiology, 2011 - nature.com
Aromatic compounds are both common growth substrates for microorganisms and
prominent environmental pollutants. The crucial step in their degradation is overcoming the …

Quantum chemical studies of mechanisms for metalloenzymes

MRA Blomberg, T Borowski, F Himo, RZ Liao… - Chemical …, 2014 - ACS Publications
Two decades ago, theoretical model calculations played a truly minor role in understanding
mechanisms of redox-active metalloenzymes. The methods available to treat transition …

Using Computational Chemistry to Reveal Nature's Blueprints for Single-Site Catalysis of C–H Activation

A Nandy, H Adamji, DW Kastner, V Vennelakanti… - ACS …, 2022 - ACS Publications
The challenge of activating inert C–H bonds motivates a study of catalysts that draws from
what can be accomplished by natural enzymes and translates these advantageous features …

Anaerobic degradation of homocyclic aromatic compounds via arylcarboxyl‐coenzyme A esters: organisms, strategies and key enzymes

M Boll, C Löffler, BEL Morris… - Environmental …, 2014 - Wiley Online Library
Next to carbohydrates, aromatic compounds are the second most abundant class of natural
organic molecules in living organic matter but also make up a significant proportion of fossil …

Bacterial steroid hydroxylases: enzyme classes, their functions and comparison of their catalytic mechanisms

M Szaleniec, AM Wojtkiewicz, R Bernhardt… - Applied Microbiology …, 2018 - Springer
The steroid superfamily includes a wide range of compounds that are essential for living
organisms of the animal and plant kingdoms. Structural modifications of steroids highly affect …

[HTML][HTML] The prokaryotic Mo/W-bisPGD enzymes family: a catalytic workhorse in bioenergetic

S Grimaldi, B Schoepp-Cothenet, P Ceccaldi… - … et Biophysica Acta (BBA …, 2013 - Elsevier
Over the past two decades, prominent importance of molybdenum-containing enzymes in
prokaryotes has been put forward by studies originating from different fields. Proteomic or …

BN/CC Isosteric Compounds as Enzyme Inhibitors: N‐ and B‐Ethyl‐1,2‐azaborine Inhibit Ethylbenzene Hydroxylation as Nonconvertible Substrate Analogues

DH Knack, JL Marshall, GP Harlow… - Angewandte Chemie …, 2013 - Wiley Online Library
Good substrate gone bad! BN/CC isosterism of ethylbenzene leads to N‐ethyl‐1, 2‐
azaborine and B‐ethyl‐1, 2‐azaborine. In contrast to ethylbenzene, which is the substrate …

Soil microbiome response to contamination with bisphenol A, bisphenol F and bisphenol S

M Zaborowska, J Wyszkowska, A Borowik - International Journal of …, 2020 - mdpi.com
The choice of the study objective was affected by numerous controversies and concerns
around bisphenol F (BPF) and bisphenol S (BPS)—analogues of bisphenol A (BPA). The …

Molybdenum and tungsten-containing enzymes: an overview

LB Maia, I Moura, JJG Moura - 2016 - books.rsc.org
Molybdenum and tungsten are heavy metallic elements, belonging to the sixth group of the
“d-block” of the periodic table, with electronic configurations [Kr] 4d5 5s1 and [Xe] 4f 14 5d4 …