The net rate of a reversible chemical reaction is the difference between unidirectional rates
of traversal along forward and reverse reaction paths. In a multistep reaction sequence, the …

The concepts of equilibrium and nonequilibrium steady states are introduced in the present
review as mathematical concepts associated with stationary Markov processes. For both …

This year we celebrate the 150th anniversary of the law of mass action. This law is often
assumed to have been “there” forever, but it has its own history, background, and a definite …

This Glossary contains definitions, explanatory notes, and sources for terms used in physical
organic chemistry. Its aim is to provide guidance on the terminology of physical organic …

Since the report of photomagnetic effects in Prussian blue Fe/Co networks 20 years ago by
the Japanese group of Hashimoto, a substantial family of molecular analogs have been …

In the context of global warming and the greenhouse effect, the iodine–sulfur cycle is an
important method of producing hydrogen on a large scale with low carbon emissions using …

Diffusion preserves the positivity of concentrations, therefore, multicomponent diffusion
should be nonlinear if there exist non-diagonal terms. The vast variety of nonlinear …

One notable observation of enzymatic chemical reactions is that, for a given abundance of
enzymes and substrates, temperature increases cause reaction rates to first increase …

[μ-Tris (1, 4-bis (tetrazol-1-yl) butane-N 4, N 4 ') iron (II)] bis (hexafluorophosphate),[Fe (btzb)
3](PF6) 2, crystallizes in a three-dimensional 3-fold interlocked structure featuring a sharp …

Developments in the title field have been greatly motivated by the studies of transactinoid
elements; selected experiments and their results are presented for visualization. Primarily …