Molecular chirality and its monitoring by ultrafast x-ray pulses

JR Rouxel, S Mukamel - Chemical Reviews, 2022 - ACS Publications
Major advances in X-ray sources including the development of circularly polarized and
orbital angular momentum pulses make it possible to probe matter chirality at …

Simulating coherent multidimensional spectroscopy of nonadiabatic molecular processes: From the infrared to the x-ray regime

M Kowalewski, BP Fingerhut, KE Dorfman… - Chemical …, 2017 - ACS Publications
Crossings of electronic potential energy surfaces in nuclear configuration space, known as
conical intersections, determine the rates and outcomes of a large class of photochemical …

Roadmap on quantum light spectroscopy

S Mukamel, M Freyberger, W Schleich… - Journal of physics B …, 2020 - iopscience.iop.org
Conventional spectroscopy uses classical light to detect matter properties through the
variation of its response with frequencies or time delays. Quantum light opens up new …

Ultrafast spectroscopy of photoactive molecular systems from first principles: Where we stand today and where we are going

I Conti, G Cerullo, A Nenov… - Journal of the American …, 2020 - ACS Publications
Computational spectroscopy is becoming a mandatory tool for the interpretation of the
complex, and often congested, spectral maps delivered by modern non-linear multi-pulse …

Ultrafast X-ray probes of elementary molecular events

D Keefer, SM Cavaletto, JR Rouxel… - Annual Review of …, 2023 - annualreviews.org
Elementary events that determine photochemical outcomes and molecular functionalities
happen on the femtosecond and subfemtosecond timescales. Among the most ubiquitous …

Monitoring molecular nonadiabatic dynamics with femtosecond X-ray diffraction

K Bennett, M Kowalewski… - Proceedings of the …, 2018 - National Acad Sciences
Ultrafast time-resolved X-ray scattering, made possible by free-electron laser sources,
provides a wealth of information about electronic and nuclear dynamical processes in …

Probing electronic fluxes via time-resolved x-ray scattering

G Hermann, V Pohl, G Dixit, JC Tremblay - Physical review letters, 2020 - APS
The current flux density is a vector field that can be used to describe theoretically how
electrons flow in a system out of equilibrium. In this work, we unequivocally demonstrate that …

[HTML][HTML] Monitoring nonadiabatic avoided crossing dynamics in molecules by ultrafast X-ray diffraction

M Kowalewski, K Bennett, S Mukamel - Structural Dynamics, 2017 - pubs.aip.org
We examine time-resolved X-ray diffraction from molecules in the gas phase which undergo
nonadiabatic avoided-crossing dynamics involving strongly coupled electrons and nuclei …

X-ray sum frequency diffraction for direct imaging of ultrafast electron dynamics

JR Rouxel, M Kowalewski, K Bennett, S Mukamel - Physical review letters, 2018 - APS
X-ray diffraction from molecules in the ground state produces an image of their charge
density, and time-resolved x-ray diffraction can thus monitor the motion of the nuclei …

Monitoring vibronic coherences and molecular aromaticity in photoexcited cyclooctatetraene with an X-ray probe: a simulation study

Y Nam, H Song, VM Freixas, D Keefer… - Chemical …, 2023 - pubs.rsc.org
Understanding conical intersection (CI) dynamics and subsequent conformational changes
is key for exploring and controlling photo-reactions in aromatic molecules. Monitoring of their …