Criegee intermediates meet rotational spectroscopy

C Cabezas, M Nakajima, Y Endo - International Reviews in …, 2020 - Taylor & Francis
Carbonyl oxides, R1R2COO, alternatively known as Criegee intermediates (CIs), are short-
lived molecules produced from ozonolysis of alkenes. These ozonolysis reactions yield …

Detailed mechanism and kinetics of the reaction of Criegee intermediate CH 2 OO with HCOOH investigated via infrared identification of conformers of …

CA Chung, JW Su, YP Lee - Physical Chemistry Chemical Physics, 2019 - pubs.rsc.org
The reaction of Criegee intermediate CH2OO with HCOOH is important in atmospheric
chemistry, but its mechanism and kinetics are little investigated. We recorded time-resolved …

Infrared characterization of the products and the rate coefficient of the reaction between Criegee intermediate CH 2 OO and HCl

WC Liang, PL Luo, YP Lee - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Reactions between Criegee intermediates and hydrogen halides might be significant,
particularly in the polluted urban atmosphere, because of their large rate coefficients …

Mechanism and kinetics of the reaction of the Criegee intermediate CH 2 OO with acetic acid studied using a step-scan Fourier-transform IR spectrometer

B Behera, K Takahashi, YP Lee - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
Acetic acid, CH3C (O) OH, plays an important role in the acidity of the troposphere. The
reactions of Criegee intermediates with CH3C (O) OH have been proposed to be a potential …

Temperature-Dependent Rate Coefficient for the Reaction of CH3SH with the Simplest Criegee Intermediate

YL Li, YH Lin, C Yin, K Takahashi… - The Journal of …, 2019 - ACS Publications
The kinetics of the reaction of the simplest Criegee intermediate CH2OO with CH3SH was
measured with transient IR absorption spectroscopy in a temperature-controlled flow …

Fast molecular fingerprinting with a coherent, rapidly tunable dual-comb spectrometer near 3 μm

PL Luo, EC Horng, YC Guan - Physical Chemistry Chemical Physics, 2019 - pubs.rsc.org
Molecular spectroscopy in the mid-infrared spectral range is expected to present fingerprints
of chemical species that provide a unique identification with adequate sensitivity. Dual-comb …

Absolute Infrared Absorption Cross Section of the Simplest Criegee Intermediate Near 1285.7 cm–1

YP Chang, YL Li, ML Liu, TC Ou… - The Journal of Physical …, 2018 - ACS Publications
The ν4 fundamental of the simplest Criegee intermediate, CH2OO, has been monitored with
high-resolution infrared (IR) transient absorption spectroscopy under total pressures of 4–94 …

Rate coefficient of the reaction CH 2 OO+ NO 2 probed with a quantum-cascade laser near 11 μm

PL Luo, CA Chung, YP Lee - Physical Chemistry Chemical Physics, 2019 - pubs.rsc.org
The reaction of the simplest Criegee intermediate CH2OO with NO2 is considered to be
important in atmospheric chemistry because of its prospective contribution to the decay of …

Identification, monitoring, and reaction kinetics of reactive trace species using time-resolved mid-infrared quantum cascade laser absorption spectroscopy …

ZS Mir, M Jamieson, NR Greenall… - Atmospheric …, 2022 - amt.copernicus.org
The chemistry and reaction kinetics of reactive species dominate changes to the
composition of complex chemical systems, including Earth's atmosphere. Laboratory …

Dynamics of the reaction CH 2 I+ O 2 probed via infrared emission of CO, CO 2, OH and H 2 CO

TY Chen, YP Lee - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
The reaction CH2I+ O2 has been widely employed recently for the production of the simplest
Criegee intermediate CH2OO in laboratories, but the detailed dynamics of this reaction have …