C-Alkyl glycosides occur widely in nature and are indispensable in drug development
programs, owing to their diverse range of medicinal properties. Previous synthetic efforts …

In the last two decades, titanocene monochloride has been postulated as a monoelectronic
transfer reagent capable of catalyzing an important variety of chemical transformations. In …

A concise method to directly generate benzyl radicals from benzyl alcohol derivatives has
been developed. The simple and inexpensive combination of TiCl4 (collidine)(collidine= 2 …

Aziridines activated by N‐acylation are opened to the higher substituted radical through
electron transfer from titanocene (III) complexes in a novel catalytic reaction. This reaction is …

We describe a regiodivergent epoxide opening (REO) featuring a catalyst‐controlled
synthesis of enantiomerically and diastereomerically highly enriched or pure syn‐and anti …

A catalytic system for titanocene‐catalyzed epoxide hydrosilylation is described. It features a
straightforward preparation of titanocene hydrides that leads to a reaction with low catalyst …

This study reports a photocatalytic Barbier-type allylation of various aldehydes and ketones
with allyl halides for the synthesis of homoallylic alcohols driven by dual titanium and …

We present a combined electrochemical, kinetic, and synthetic study with a novel and easily
accessible class of titanocene catalysts for catalysis in single‐electron steps. The tailoring of …

A synthetic approach to dihydropyrrolizine and tetrahydroindolizine scaffolds from pyrroles
has been developed. The key step, a titanocene (III)‐catalyzed radical arylation that …

The exceptionally mild conditions of a titanium (III)‐catalyzed cyclization reaction paired with
a convenient acid/base extraction have enabled the straightforward synthesis, isolation, and …