Since the isolation and crystallographic characterization of the first stable N-heterocyclic
carbene in early 1991, 1 nucleophilic diaminocarbenes (also known as “Arduengotype” …

2-(2-Methoxyphenyl)-1, 3-dimethyl-1 H-benzoimidazol-3-ium iodide (o-MeO-DMBI-I) was
synthesized and employed as a strong n-type dopant for fullerene C60, a well-known n …

A new class of luminescent mononuclear and dinuclear N-heterocyclic carbene-containing
gold (III) complexes has been synthesized and characterized. The X-ray crystal structures of …

1,2,4,5-Tetrazines and Azolo[1,2,4,5]tetrazines: Synthesis and Reactions with Nucleophiles |
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Further explorations of the catalytic potential of N-heterocyclic carbene (NHC) ligated
palladacycles as catalysts for Pd-mediated transformations have been hampered by the lack …

Gripping ligands: A series of fluoroalkoxy‐functionalized imidazol‐2‐ylidene ligands were
synthesized by the alkylation of a range of commercially available azoles with …

A series of triazolium salts, selected for their varying electronic and steric properties, were
prepared and their pKa values were determined in DMSO at 25° C using the bracketing …

New methods for the preparation of NHC-metal complexes have been developed. It was
shown that a nitrile group in Reissert analogous compounds can act as a good leaving …

The head‐to‐tail dimerization of N‐heterocyclic diazoolefins is described. The products of
these formal (3+ 3) cycloaddition reactions are strongly reducing quinoidal tetrazines …

Electrosynthesis of 1-methyl-3-(pyren-1-yl)-1H-imidazol-3-ium tetrafluoroborate via oxidative
C–N coupling of pyrene with methylimidazole is optimized with the aim to reduce waste and …