Iron (II) complexes of 2, 6-di (pyrazol-1-yl) pyridines—A versatile system for spin-crossover research

MA Halcrow - Coordination Chemistry Reviews, 2009 - Elsevier
Synthetic procedures are available for the derivatisation of almost every position of the 2, 6-
di (pyrazol-1-yl) pyridine (1-bpp) skeleton. This has led to the preparation of a large number …

Spin state switching in 2, 6-bis (pyrazol-3-yl) pyridine (3-bpp) based Fe (II) complexes

GA Craig, O Roubeau, G Aromi - Coordination Chemistry Reviews, 2014 - Elsevier
The area of spin crossover (SCO) attracts interest both on a fundamental level and in terms
of potential applications for compounds displaying this phenomenon. A few families of Fe (II) …

The spin-states and spin-transitions of mononuclear iron (II) complexes of nitrogen-donor ligands

MA Halcrow - Polyhedron, 2007 - Elsevier
A survey of mononuclear iron (II) complexes with heterocyclic N-donor ligation is presented.
A brief introduction to spin-crossover chemistry and low-temperature spin-trapping is …

Evolution of cooperativity in the spin transition of an iron (II) complex on a graphite surface

L Kipgen, M Bernien, S Ossinger, F Nickel… - Nature …, 2018 - nature.com
Cooperative effects determine the spin-state bistability of spin-crossover molecules (SCMs).
Herein, the ultimate scale limit at which cooperative spin switching becomes effective is …

A critical review of the T (LIESST) temperature in spin crossover materials− What it is and what it is not

G Chastanet, C Desplanches, C Baldé… - Chemistry Squared …, 2018 - hal.science
Light-Induced Excited Spin-State Trapping has been studied since 1982 in solution and
1984 in solid state as it offers a reversible way of photoswitching the electronic configuration …

Trapping and manipulating excited spin states of transition metal compounds

MA Halcrow - Chemical Society Reviews, 2008 - pubs.rsc.org
This tutorial review describes how complexes of iron (II)(and, rarely, other metal ions) can be
switched between their high-and low-spin states by different physical stimuli. At low …

Cooperative Iron(II) Spin Crossover Complexes with N4O2 Coordination Sphere

B Weber, E Kaps, J Weigand, C Carbonera… - Inorganic …, 2008 - ACS Publications
Two new spin crossover complexes [FeL (py) 2](1) and [FeL (DMAP) 2](2) with L being a
tetradentate N2O22-coordinating Schiff-base-like ligand [([3, 3 ']-[1, 2-phenylenebis …

Defying the inverse energy gap law: a vacuum-evaporable Fe (ii) low-spin complex with a long-lived LIESST state

J Grunwald, J Torres, A Buchholz, C Näther… - Chemical …, 2023 - pubs.rsc.org
The novel vacuum-evaporable complex [Fe (pypypyr) 2](pypypyr= bipyridyl pyrrolide) was
synthesised and analysed as bulk material and as a thin film. In both cases, the compound is …

Coordination versatility of 1, 3-bis [3-(2-pyridyl) pyrazol-1-yl] propane: Co (II) and Ni (II) complexes

V Mishra, F Lloret, R Mukherjee - Inorganica chimica acta, 2006 - Elsevier
The ligand 1, 3-bis [3-(2-pyridyl) pyrazol-1-yl] propane (L8) has afforded six-coordinate
monomeric and dimeric complexes [(L8) CoII (H2O) 2][ClO4] 2 (1),[(L8) NiII (MeCN) 2][BPh4] …

High-temperature photo-induced switching and pressure-induced transition in a cooperative molecular spin-crossover material

GA Craig, JS Costa, O Roubeau, SJ Teat… - Dalton …, 2014 - pubs.rsc.org
The thermal and photo-induced switching properties of the recently published molecular
spin crossover complex [Fe (H4L) 2](ClO4) 2· H2O· 2 (CH3) 2CO (1) have been investigated …