Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping
Y Zhang, D Fu, Z Chen, R Cui, W He, H Wang… - Nature …, 2024 - nature.com
The challenging synthesis of thermodynamic-unfavored cis-olefins through catalytic cross-
coupling reactions requires the synergistic interaction of substrate-activating units and …
coupling reactions requires the synergistic interaction of substrate-activating units and …
Iron in Organometallic Transformations: A Sustainable Substitute for Noble Metals
Transition metal catalysis plays a pivotal role in chemical synthesis. Noble metals often grab
significant attention in organometallic catalysis due to their high reactivity. However, the …
significant attention in organometallic catalysis due to their high reactivity. However, the …
Ligand-Free Iron-Catalyzed Carbonylation of Aryl Iodides with Alkenyl Boronic Acids: Access to α, β-Unsaturated Ketones
N Xu, J Chen, K Sun, W Han - Organic Letters, 2024 - ACS Publications
The application of earth-abundant and low-toxicity iron catalysts as replacements for
palladium in carbonylative coupling reactions remains challenging and largely unexplored …
palladium in carbonylative coupling reactions remains challenging and largely unexplored …
Iron-Catalyzed Chemoselective Transfer Hydrogenation of α,β-Unsaturated Ketones Using H2O as a Surrogate of Hydrogen
Sustainable and highly economical iron-catalyzed chemoselective reduction of C═ C of α, β-
unsaturated ketones has been established under mild reaction protocols. Water is used as a …
unsaturated ketones has been established under mild reaction protocols. Water is used as a …