A hierarchical single-pulse shock tube pyrolysis study of C2–C6 1-alkenes

SS Nagaraja, J Liang, S Dong, S Panigrahy… - Combustion and …, 2020 - Elsevier
A single-pulse shock tube study of the pyrolysis of 2% C 2–C 6 1-alkenes is presented at 2
bar in the temperature range 900–1800 K in the current study. Reactant, intermediate and …

A single pulse shock tube study of pentene isomer pyrolysis

SS Nagaraja, J Power, G Kukkadapu, S Dong… - Proceedings of the …, 2021 - Elsevier
A single-pulse shock tube study of the four pentene isomers is carried out at 2±0.16 bar and
900–1600 K. C 1 to C 6 species profiles were recorded using gas chromatography mass …

PAH formation from jet stirred reactor pyrolysis of gasoline surrogates

C Shao, G Kukkadapu, SW Wagnon, WJ Pitz… - Combustion and …, 2020 - Elsevier
Soot particles and their precursor polycyclic aromatic hydrocarbon (PAH) species, formed
during combustion, are responsible for particulate emissions in gasoline direct injection …

The morphological transformation of carbon materials from nanospheres to graphene nanoflakes by thermal plasma

X Chen, C Wang, M Song, J Ma, T Ye, W Xia - Carbon, 2019 - Elsevier
Carbon materials are synthesized by the thermal decomposition of acetylene using a
magnetically rotating arc under atmospheric pressure. The effects of hydrogen addition, gas …

Fundamentally-based kinetic model for propene pyrolysis

K Wang, SM Villano, AM Dean - Combustion and Flame, 2015 - Elsevier
The primary objective of this work is to develop an improved fundamentally-based
mechanism that describes the molecular weight growth kinetics observed during propene …

Polycyclic aromatic hydrocarbon (PAH) formation from benzyl radicals: a reaction kinetics study

S Sinha, A Raj - Physical Chemistry Chemical Physics, 2016 - pubs.rsc.org
The role of resonantly stabilized radicals such as propargyl, cyclopentadienyl and benzyl in
the formation of aromatic hydrocarbons such as benzene and naphthalene in the high …

Cyclopentane combustion chemistry. Part I: Mechanism development and computational kinetics

MJ Al Rashidi, M Mehl, WJ Pitz, S Mohamed… - Combustion and …, 2017 - Elsevier
Cycloalkanes are significant constituents of conventional fossil fuels, in which they are one
of the main contributors to soot formation, but also significantly influence the ignition …

Cyclopentane combustion. Part II. Ignition delay measurements and mechanism validation

MJ Al Rashidi, JC Mármol, C Banyon, MB Sajid… - Combustion and …, 2017 - Elsevier
This study reports cyclopentane ignition delay measurements over a wide range of
conditions. The measurements were obtained using two shock tubes and a rapid …

[HTML][HTML] Kinetic modeling of soot formation in premixed burner-stabilized stagnation ethylene flames at heavily sooting condition

A detailed kinetic mechanism of soot formation and oxidation is revised and extended to
include temperature-dependent collision efficiencies. The collision efficiency for various …

Reactivity–structure-based rate estimation rules for alkyl radical H atom shift and alkenyl radical cycloaddition reactions

K Wang, SM Villano, AM Dean - The Journal of Physical Chemistry …, 2015 - ACS Publications
Intramolecular H atom shift reactions of alkyl radicals and cycloaddition reactions of alkenyl
radicals are two important reaction classes in hydrocarbon combustion and pyrolysis. In this …