Structural origin of relaxation in dense colloidal suspensions

R Sahu, M Sharma, P Schall… - Proceedings of the …, 2024 - pnas.org
Amorphous solids relax via slow molecular rearrangement induced by thermal fluctuations
or applied stress. Microscopic structural signatures predicting these structural relaxations …

Continuum modeling of shear startup in soft glassy materials

R Benzi, T Divoux, C Barentin, S Manneville… - Physical Review E, 2021 - APS
Yield stress fluids (YSFs) display a dual nature highlighted by the existence of a critical
stress σ y such that YSFs are solid for stresses σ imposed below σ y, whereas they flow like …

Rheological signatures of aging in hard sphere colloidal glasses

AR Jacob, E Moghimi, G Petekidis - Physics of Fluids, 2019 - pubs.aip.org
Colloidal glasses are out-of-equilibrium in nature. When such materials are quenched from
a shear-melted state into a quiescent one, their structure freezes due to entropic caging of …

[HTML][HTML] Transient dynamics of soft particle glasses in startup shear flow. Part I: Microstructure and time scales

F Khabaz, BF Di Dio, M Cloitre, RT Bonnecaze - Journal of Rheology, 2021 - pubs.aip.org
The rheology and microstructure of soft particle glasses during startup flow are studied using
three-dimensional particle dynamics simulations at different particle volume fractions and …

Mechanisms of two-step yielding in attractive colloidal glasses

E Moghimi, G Petekidis - Journal of Rheology, 2020 - pubs.aip.org
A combination of experiments and Brownian Dynamics simulations is utilized to examine the
mechanisms of yielding and flow in attractive colloidal glasses during start-up shear flow. In …

Elastic and flow properties of densely packed binary microgel mixtures with size and stiffness disparities

A Nakaishi, S Minami, S Oura, T Watanabe… - …, 2018 - ACS Publications
Densely packed soft microgels (pastes) behave as a yield-stress fluid. They act as soft
elastic solids with finite equilibrium shear modulus (G 0) below a critical stress (σc) whereas …

Colloidal and polymeric contributions to the yielding of dense microgel suspensions

MA Lara-Peña, A Licea-Claverie… - Journal of Colloid and …, 2021 - Elsevier
Hypothesis Soft microgel colloids can be densely packed since particle networks can
compress and interpenetrate. This evolution of the particle's internal structure associated …

Stress versus strain controlled shear: Yielding and relaxation of concentrated colloidal suspensions

A Pamvouxoglou, AB Schofield, G Petekidis… - Journal of …, 2021 - pubs.aip.org
In rheological experiments, the relationship between stress and strain is determined. In the
transient regime, this relationship may depend on which of these properties is applied and …

Yielding characterization of waxy gels by energy dissipation

H Liu, J Zhang, Y Lu - Rheologica Acta, 2018 - Springer
The rheological behaviors of yield stress fluids are commonly interpreted from the energy
perspective, yet this perspective has rarely been applied for waxy gel. In this study, we …

Mechanical response and yielding transition of silk-fibroin and silk-fibroin/cellulose nanocrystals composite gels

G Poggi, D Chelazzi, M Laurati - Colloids and Surfaces A: Physicochemical …, 2022 - Elsevier
We investigated the mechanical properties of gels formed by silk fibroin and silk
fibroin/cellulose nanocrystal mixtures. Viscosity and linear viscoelasticity measurements …