Singlet Oxygen Generation, Quenching and Reactivity with Metal Thiolates

CG Monsour, CM Decosto… - Photochemistry and …, 2021 - Wiley Online Library
Metal thiolate complexes can act as photosensitizers for the generation of singlet oxygen,
quenchers of singlet oxygen, and they may undergo chemical reactions with singlet oxygen …

Self-Catalysis Transformation of Metal–Organic Coordination Polymers

F Fan, L Zhao, Q Zeng, L Zhang, X Zhang… - … Applied Materials & …, 2023 - ACS Publications
Designing a multidimensional transformation of metal–organic coordination polymers
(MOPs) is highly attractive yet very challenging. Herein, by combining the dynamicity of the …

Dual-Function Precious-Metal-Free Metal–Organic Framework for Photocatalytic Conversion and Chemical Fixation of Carbon Dioxide

X Wang, J Li, M Kou, W Dou, D Bai, X Tang… - Inorganic …, 2023 - ACS Publications
Highly efficient transformation of carbon dioxide (CO2) into value-added chemicals is
considered a promising route for clean production and future energy sustainability, which is …

Use of singlet oxygen in the generation of a mononuclear nonheme iron (IV)-Oxo complex

W Zhu, N Sharma, YM Lee, ME El-Khouly… - Inorganic …, 2023 - ACS Publications
Nonheme iron (III)-superoxo intermediates are generated in the activation of dioxygen (O2)
by nonheme iron (II) complexes and then converted to iron (IV)-oxo species by reacting with …

Photooxidation reactions of cyclometalated palladium (ii) and platinum (II) complexes

J Yasuda, K Inoue, K Mizuno, S Arai, K Uehara… - Inorganic …, 2019 - ACS Publications
New C, N, S-cyclometalated palladium (II) and platinum (II) complexes have been
synthesized and their structural, electrochemical, and photochemical properties examined …

Thermodynamic Resolution and Enantioselective Synthesis of C2-Symmetric Bis-sulfoxides Based on Chiral Iridium(III) Complexes

LP Li, HL Peng, BH Ye - Inorganic Chemistry, 2019 - ACS Publications
Enantiopure Λ-[Ir (dfppy) 2 (MeCN) 2](PF6) and Δ-[Ir (dfppy) 2 (MeCN) 2](PF6)(where dfppy
is (4, 6-difluoropheny) pyridine) were demonstrated to preferentially react with (S, S)-1, 2-bis …

Thermodynamic Resolution of Pharmaceutical Precursor Modafinil Acid on the Basis of Chiral‐at‐Metal Strategy

ML Cao, JL Zhu, ZL Zhi, BH Ye, SY Yao… - Chinese Journal of …, 2021 - Wiley Online Library
Main observation and conclusion Chiral‐at‐metal strategy was developed to resolve the
essential sulfoxide pharmaceutical intermediates R‐modafinil acid and its analogues with …

Synthesis of mono/dinuclear rhenium (i) tricarbonyl substituted with 4-mercaptopyridine related ligands: spectral and theoretical evidence of thiolate/thione …

A Gomez, G Jara, E Flores, T Maldonado… - New Journal of …, 2020 - pubs.rsc.org
The synthesis, characterization and spectroscopic and theoretical studies of new κ1-S
monometallic Re-spy (1)/Re-thiopy (2) and κ1-N-bimetallic Re2-dps (3)/Re2-dpds (4) …

Chemistry of Singlet Oxygen with a Cadmium–Sulfur Cluster: Physical Quenching versus Photooxidation

DA Cagan, AC Garcia, K Li… - Journal of the …, 2018 - ACS Publications
We investigated the chemistry of singlet oxygen with a cadmium–sulfur cluster,(Me4N) 2
[Cd4 (SPh) 10]. This cluster was used as a model for cadmium–sulfur nanoparticles. Such …

Chemistry of ternary monocarboxyterpyridine-bipyridine-trimercaptotriazine ruthenium complexes and application in dye sensitized solar cells

JS Aguirre-Araque, RR Guimaraes, HE Toma - Polyhedron, 2020 - Elsevier
The synthesis of the [Ru II (Hmctpy)(H 2 O)(Cl 2)],[Ru II (Hmctpy)(dmbpy) Cl] Cl and [Ru II
(Hmctpy)(dmbpy)(H 3 tmt)](PF 6) 2 complexes (mctpy= monocarboxyterpyridine, dmbpy …