Enzymes, In Vivo Biocatalysis, and Metabolic Engineering for Enabling a Circular Economy and Sustainability

P Intasian, K Prakinee, A Phintha, D Trisrivirat… - Chemical …, 2021 - ACS Publications
Since the industrial revolution, the rapid growth and development of global industries have
depended largely upon the utilization of coal-derived chemicals, and more recently, the …

Toward a mechanistic understanding of electrocatalytic nanocarbon

EJ Askins, MR Zoric, M Li, Z Luo, K Amine… - Nature …, 2021 - nature.com
Electrocatalytic nanocarbon (EN) is a class of material receiving intense interest as a
potential replacement for expensive, metal-based electrocatalysts for energy conversion and …

Triarylmethyl cation redox mediators enhance Li–O2 battery discharge capacities

EJ Askins, MR Zoric, M Li, R Amine, K Amine… - Nature Chemistry, 2023 - nature.com
A major impediment to Li–O2 battery commercialization is the low discharge capacities
resulting from electronically insulating Li2O2 film growth on carbon electrodes. Redox …

Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy

W Xie, J Xu, U Md Idros, J Katsuhira, M Fuki… - Nature Chemistry, 2023 - nature.com
Increasing levels of CO2 in the atmosphere is a problem that must be urgently resolved if the
rise in current global temperatures is to be slowed. Chemically reducing CO2 into …

Exploiting the NADP+/NADPH-like Hydride-Transfer Redox Cycle with Bis-Imidazolium-Embedded Heterohelicene for Electrocatalytic Hydrogen Evolution Reaction

P Karak, SK Mandal, J Choudhury - Journal of the American …, 2023 - ACS Publications
Generation of clean energy in a viable manner demands efficient and sustainable catalysts.
One prospective method of clean energy generation is the electrochemical hydrogen …

Triarylamine-Substituted Benzimidazoliums as Electron Donor–Acceptor Dyad-Type Photocatalysts for Reductive Organic Transformations

R Miyajima, Y Ooe, T Miura, T Ikoma… - Journal of the …, 2023 - ACS Publications
Triarylamine-substituted benzimidazoliums (BI+–PhNAr2), new electron donor–acceptor
dyad molecules, were synthesized. Their photocatalytic properties for reductive organic …

Light-Driven Reduction of CO2 to CO in Water with a Cobalt Molecular Catalyst and an Organic Sensitizer

PY Ho, SC Cheng, F Yu, YY Yeung, WX Ni, CC Ko… - ACS …, 2023 - ACS Publications
We report an efficient visible light-driven CO2 reduction system that functions in water and
without any noble metal nor rare materials. Using the cobalt complex [Co (qpy)(OH2) 2] …

Bis-Imidazolium-Embedded Heterohelicene: A Regenerable NADP+ Cofactor Analogue for Electrocatalytic CO2 Reduction

P Karak, SK Mandal, J Choudhury - Journal of the American …, 2023 - ACS Publications
Biomimetic NAD (P) H-type organic hydride donors have recently been advocated as
potential candidates to act as metal-free catalysts for fuel-forming reactions such as the …

Photochemical charge accumulation in a heteroleptic copper (I)-anthraquinone molecular dyad via proton-coupled electron transfer

ZL Xie, N Gupta, J Niklas, OG Poluektov, VM Lynch… - Chemical …, 2023 - pubs.rsc.org
Developing efficient photocatalysts that perform multi electron redox reactions is critical to
achieving solar energy conversion. One can reach this goal by developing systems which …

Metallated dihydropyridinates: prospects in hydride transfer and (electro) catalysis

LWT Parsons, LA Berben - Chemical Science, 2023 - pubs.rsc.org
Hydride transfer (HT) is a fundamental step in a wide range of reaction pathways, including
those mediated by dihydropyridinates (DHP− s). Coordination of ions directly to the pyridine …