Rational design of a room temperature molecular spin switch. The light-driven coordination induced spin state switch (LD-CISSS) approach

M Dommaschk, C Schütt, S Venkataramani… - Dalton …, 2014 - pubs.rsc.org
Extensive use of quantum chemical calculations has been made to rationally design a
molecule whose spin state can be switched reversibly using light of two different …

Modulation of the ligand-based fluorescence of 3d metal complexes upon spin state change

C Lochenie, KG Wagner, M Karg… - Journal of Materials …, 2015 - pubs.rsc.org
Two new Schiff base-like ligands bearing a heteroaromatic fluorophore were synthesised
and converted into the corresponding Ni (II), Cu (II) and Zn (II) square planar complexes. The …

Excited-state proton-coupled electron transfer within ion pairs

WB Swords, GJ Meyer, L Hammarström - Chemical Science, 2020 - pubs.rsc.org
The use of light to drive proton-coupled electron transfer (PCET) reactions has received
growing interest, with recent focus on the direct use of excited states in PCET reactions (ES …

Incorporation of spin-crossover cobalt (II) complexes into conducting metallopolymers: Towards redox-controlled spin change

MT Nguyen, RA Jones, BJ Holliday - Polymer, 2021 - Elsevier
Metal complexes from cobalt (II/III) ions with two tridentate ligands and the corresponding
conducting metallopolymers have been synthesized, characterized and subjected to …

Coordination-induced spin-state change in manganese (V) complexes: the electronic structure of manganese (V) nitrides

H Kropp, A Scheurer, FW Heinemann… - Inorganic …, 2015 - ACS Publications
This work illustrates that manganese (V) nitrido complexes are able to undergo a
coordination-induced spin-state change by altering the ligand field from trigonal to …

A new Ni (II) metalloporphyrin: characterization, theoretical sensing calculations and catalytic degradation of methylene blue and methyl orange dyes

MA Bouicha, N Moulahi, M Guergueb… - Journal of the Iranian …, 2024 - Springer
With the aim of studying the electronic and structural properties of metalloporphyrins, we first
prepared the 4-acetoxy-3-methoxy benzaldehyde (1) then by reaction this aldehyde with …

Fabrication of carbon nanotube-multiporphyrin array composites as light-sensitizer for photocurrent generation, photochromism of viologen and catalytic degradation …

J Wang, WL He, M Chen, DJ Qian - New Journal of Chemistry, 2018 - pubs.rsc.org
Multiporphyrin arrays play an important role as active light-sensitizers in photo-induced
energy and electron transfer processes. Here, we report a palladium-directed self-assembly …

Modulation of axial-ligand binding and releasing processes onto the triazole-bearing nickel (II) picket-fence porphyrins: steric repulsion versus hydrogen-bonding …

J Oh, H Yoon, YM Sung, P Kang, MG Choi… - The Journal of …, 2015 - ACS Publications
N-(p-Methoxycarbonylbenzyl) triazole (BTz) substituents have been introduced to Ni (II)
porphyrins (NiPs), in which their modulated axial-coordination processes have been …

Spectroscopic Investigation of the Remote C–H Allylation of Amides via Photoredox and Nickel Dual Catalysis

C Bourgois, S De Kreijger, B Xu, UK Tambar… - Synlett, 2024 - thieme-connect.com
The mechanistic details of a reported allylation reaction are investigated by means of Stern–
Volmer experiments and nanosecond transient absorption spectroscopy. Both reference …

Enhanced Photocatalytic Performance of Porphyrin/Phthalocyanine and Bis(4‐pyridyl)pyrrolidinofullerene modified Titania

E Regulska, DM Rivera‐Nazario, J Karpinska… - …, 2017 - Wiley Online Library
Abstract Zinc (II), copper (II) and cobalt (II) metallated porphyrins/phthalocyanines and bis (4‐
pyridyl) pyrrolidinofullerene (9) were used in a supramolecular approach for the …