Abstract In 2010, Richard Heck, Ei‐ichi Negishi, and Akira Suzuki joined the prestigious
circle of Nobel Laureate chemists for their roles in discovering and developing highly …

Organic chemists have always been fascinated by the cyclopropane subunit. 1 The smallest
cycloalkane is found as a basic structural element in a wide range of naturally occurring …

Amidst burgeoning interest, atomically precise copper nanoclusters (Cu NCs) have emerged
as a remarkable class of nanomaterials distinguished by their unparalleled reactivity …

At last count, nearly 5000 halogenated natural products have been discovered. In
approximately half of these compounds, the carbon atom to which the halogen is bound is …

The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews …

Sonogashira coupling involves coupling of vinyl/aryl halides with terminal acetylenes
catalyzed by transition metals, especially palladium and copper. This is a well known …

Abstract Im Jahr 2010 wurden Richard Heck, Ei‐ichi Negishi und Akira Suzuki in den
illustren Kreis der Chemie‐Nobelpreisträger aufgenommen. Begründet wurde diese …

Ever since the first isolation of Exaltolide 1 (Figure 1) in 1927 by Kerschbaum, 1 interest in
macrocyclic lactones, defined as lactones with more than 8 atoms in the ring, has been …

The aldol reaction is one of the most important methods for the stereoselective construction
of polyketide natural products, not only for nature but also for synthetic chemistry. The …

This review will focus on selected applications of Sonogashira coupling and subsequent
transformations as key steps in the total synthesis of natural products. A brief introduction to …