Metallacyclopentadienes, which possess two M–C (sp2) bonds and feature the structure of
M (CR1CR2–CR3CR4), are an important class of five-membered metallacycles. They are …

A mild, metal-free synthesis of pyrido [1, 2-a] benzimidazoles starting with N-benzyl-2-
aminopyridines, which employs PhI (OPiv) 2 as a stoichiometric oxidant, has been …

We have synthesized a new type of metallaaromatic complexes, namely the hydride-β-
iridanaphthalenes TpMe2 r (H)[C (CH2R′)-C6H4-oC (R) C (R)](benzo-3-H, CH2R′), by …

This is a review of papers published in the year 2012 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon-transition metal double or triple bond.

The first well‐defined lutetacyclopentadienes are synthesised from
pentamethylcyclopentadienyl lithium (Cp* Li), 1, 4‐dilithio‐1, 3‐butadienes, and LuCl3. The …

Ethylene glycol (EG) has been widely utilized to fabricate silver nanoparticles with uniform
size and morphology. However, the majority of the work reported to date using EG routinely …

Synthesis and characterization of metallacycles is an important research issue because they
have acted as important building blocks and key intermediates in synthetic and catalytic …

The sandwich lutetacyclopentadiene 2 can be obtained in high yield by the 1: 1 reaction of
the 1, 4-dilithio-1, 3-butadiene 1 with [Cp2LuCl]. Single-crystal X-ray diffraction of 2 reveals it …

A transition-metal-free conversion of 2-arylindoles to 2-aminoarylphenones, using
environmentally benign O2 as the sole oxidant, has been developed. This novel oxidative …

The reactivity of different heteroscorpionate ligands based on bis (pyrazol-1-yl) methane,
with different iridium-(I) and-(III) precursors is reported. The reaction of the heteroscorpionate …