Chiral boronic esters are a class of versatile building blocks. We describe herein an
asymmetric nickel-catalyzed borylative coupling of terminal alkenes with nonactivated alkyl …

Dicarboxylic acids and derivatives are important building blocks in organic synthesis,
biochemistry, and the polymer industry. Although catalytic dicarboxylation with CO2 …

Catalytic asymmetric carboxylation of readily available alkenes with CO2, an abundant and
sustainable one-carbon building block, that gives access to value-added α-stereogenic …

In contrast to previous approaches to chiral α‐aryl carboxylic acids that based on reactions
using hazardous gases, pressurized setup and mostly noble metal catalysts, in this work, a …

Novel strategy for acid chlorides formation that do not use carboxylic acids is particularly
attractive in chemical synthesis but remains challenging. Herein, we reported the …

Single metal/multiligand catalysis (SMMLC) has recently been developed for the highly
efficient and selective synthesis of valuable compounds. As a newly emerged member of …

Catalytic cascade transformations of simple starting materials into highly functionalized
molecules bearing a stereochemically defined multisubstituted alkene, which are important …

Catalytic asymmetric hydroboration of unsaturated bonds has been recognized as the most
straightforward method for the construction of chiral organoboron compounds. Although …

A Pd‐catalyzed asymmetric isomerization‐hydroamidocarbonylation of amide‐containing
alkenes was developed, affording a variety of chiral α‐alkyl succinimides in moderate to …

We herein disclose a mild and efficient access to chiral 3‐azabicyclo [3.1. 0] hexanes via a
Pd‐catalyzed asymmetric 5‐exo‐trig cyclization/cyclopropanation/carbonylation of 1, 6 …