We developed a bench-stable iminopyridine-ligated zinc complex for the effective catalytic
hydroboration of esters and nitriles under solvent-free conditions. Various esters and nitriles …

Abstract Cyclic organoalane compounds [(ADCAr) AlH2] 2 (ADCAr= ArC {(DippN) C} 2;
Dipp= 2, 6‐iPr2C6H3; Ar= Ph or 4‐PhC6H4 (Bp)) based on anionic dicarbene (ADC) …

A novel, simple, eco-friendly, non-toxic aluminium catalyst was synthesised for the
chemoselective reduction of α, β-unsaturated ketones. A wide range of ketones were …

The reduction in esters, nitriles, and imines requires harsh conditions (highly reactive
reagents, high temperatures, and pressures) or complex metal-ligand catalytic systems …

Static catalysis using neutral and cationic Al (III) complexes, in which the oxidation state of
the metal does not change, can be applied to a range of catalytic bond‐forming reactions …

Regioselective epoxide ring-opening through hydroboration catalysed by a vanadium (III)
dialkyl complex supported by a redox-active terpyridine ligand is reported. Secondary …

Boron-based frustrated Lewis pairs (FLPs) have become well-established catalysts for the
hydrogenation of a wide range of functional groups. Conversely, aluminium-based FLP …

The conjugated bis-guanidinate (CBG)-supported zinc hydride {LZnH} 2; L={(ArHN)(ArN)–
CN–C (NAr)(NHAr); Ar= 2, 6-Et2-C6H3}(I) is utilized as a catalyst for the hydroboration of …

Amino‐functionalized β‐diketiminate stabilized chlorogermylene 1 and chlorostannylene 2
have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu …

This procedure entails the incorporation of hydrogen gas (H 2) into an ester compound,
leading to the creation of an alcohol. This shift holds great significance in diverse domains …