Indoline is an important structural motif present in several biologically active compounds
from both natural and synthetic origins. The occurrence of this heterocyclic unity in these …

A dehydrogenative [3+ 2] annulation reaction of aniline derivatives and alkenes has been
developed via the ruthenium-electron catalytic systems for the synthesis of versatile …

Radical–radical cyclization cascades, triggered by single-electron transfer to amide-type
carbonyls by SmI2–H2O, convert simple achiral barbiturates in one step to hemiaminal-or …

Highly selective dearomatizing radical cyclizations and cyclization cascades, triggered by
single electron transfer to amide-type carbonyls by SmI2–H2O–LiBr, provide efficient access …

Radical anions generated from urea carbonyls by reductive electron transfer are exploited in
carbon–carbon bond formation. New radical cyclizations of urea radical anions deliver …

Methylation of sulfones, which have an α-CH bond, can be easily achieved via a one-step,
Ru (II) catalyzed redox neutral reaction using methanol as a sustainable C1 building block …

The Rh (III)-catalyzed reaction of aniline derivatives that contain a pyrimidine directing group
with vinylsilanes results in the formation of C3-substituted indoline derivatives in a highly …

An efficient protocol for the hydroboration of imines is reported. Lithium halide salts are
effective catalysts to convert aldimines and ketimines to their corresponding amines. Here …

Radical heterocyclizations triggered by electron transfer to amide‐type carbonyls, using
SmI2‐H2O, provide straightforward access to bicyclic heterocyclic scaffolds containing …

A palladium‐catalyzed dearomatizing difunctionalization of N‐Boc‐indoles and benzofurans
to give tricyclic indolines and 2, 3‐dihydrobenzofurans with a fully substituted carbon center …