Predictive synthesis

K Kovnir - Chemistry of Materials, 2021 - ACS Publications
Current solid state synthesis intrinsically involves a multidimensional space which is
challenging to parametrize and predict. The diversity of extended structures comes from the …

Syntheses of five new layered quaternary chalcogenides SrScCuSe 3, SrScCuTe 3, BaScCuSe 3, BaScCuTe 3, and BaScAgTe 3: Crystal structures, thermoelectric …

M Ishtiyak, S Jana, R Karthikeyan, M Ramesh… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Copper/silver-containing chalcogenides have recently attracted significant interest for their
promising thermoelectric applications. In this article, we report the syntheses of five new …

Topotactic BI 3-assisted borodization: synthesis and electrocatalysis applications of transition metal borides

KE Woo, S Kong, W Chen, TH Chang… - Journal of Materials …, 2022 - pubs.rsc.org
A facile and universal route for synthesizing transition metal borides has been developed by
reaction of boron triiodide (BI3) with elemental transition metals. This method employs …

Germanium Antimony Bonding in Ba4Ge2Sb2Te10 with Low Thermal Conductivity

S Jana, G Panigrahi, M Ishtiyak… - Inorganic …, 2021 - ACS Publications
A new quaternary telluride, Ba4Ge2Sb2Te10, was synthesized at high temperature via the
reaction of elements. A single-crystal X-ray diffraction study shows that the title compound …

Metal to insulator transition in Ba2Ge2Te5: Synthesis, crystal structure, resistivity, thermal conductivity, and electronic structure

S Jana, M Ishtiyak, L Govindaraj, S Arumugam… - Materials Research …, 2022 - Elsevier
A monophasic polycrystalline sample of Ba 2 Ge 2 Te 5 has been synthesized for the first
time using the sealed tube solid-state method. The Rietveld refinement of a polycrystalline …

Semiconducting silicon–phosphorus frameworks for caging exotic polycations

P Yox, AP Porter, RW Dorn, V Kyveryga… - Chemical …, 2022 - pubs.rsc.org
A series of novel semiconductors AAe6Si12P20X (A= Na, K, Rb, Cs; Ae= Sr, Ba; X= Cl, Br, I)
is reported. Their crystal structures feature a tetrahedral Si–P framework with large zeolite …

Sodium Filling in Superadamantoide Na1.36(Si0.86Ga0.14)2As2.98 and the Mixed Valent Arsenidosilicate-Silicide Li1.5Ga0.9Si3.1As4

M Schöneich, LG Balzat, BV Lotsch, D Johrendt - Inorganics, 2024 - mdpi.com
Na1. 36 (Si0. 86Ga0. 14) 2As2. 98 and Li1. 5Ga0. 9Si3. 1As4 were synthesized by heating
mixtures of the elements at 950° C. The crystal structures were determined by single crystal …

Supertetrahedral anions in the phosphidosilicates Na 1.25 Ba 0.875 Si 3 P 5 and Na 31 Ba 5 Si 52 P 83

A Haffner, OEO Zeman, T Bräuniger, D Johrendt - Dalton Transactions, 2021 - pubs.rsc.org
Solid ionic conductors are one key component of all-solid-state batteries, and recent studies
with lithium, sodium and potassium phosphidosilicates revealed remarkable ion conduction …

Electrοn crystallοgraphy οf nanοparticles

EC Oyonarte - 2024 - theses.hal.science
Nanoparticles (NPs) are of great interest due to their unique properties, making them useful
in different scientific fields. Understanding the crystallographic structure of NPs is crucial for …