Chiral allylic and allenic stannanes as reagents for asymmetric synthesis

JA Marshall - Chemical reviews, 1996 - ACS Publications
In the synthesis of complex natural products one is frequently confronted with the task of
creating intermediates possessing multiple contiguous stereogenic centers. Two important …

The chemistry and biology of the bryostatin antitumour macrolides

KJ Hale, MG Hummersone, S Manaviazar… - Natural product …, 2002 - pubs.rsc.org
The chemistry and biology of the bryostatin antitumour macrolides - Natural Product Reports
(RSC Publishing) DOI:10.1039/B009211H Royal Society of Chemistry View PDF VersionPrevious …

Designed iron catalysts for allylic C− H functionalization of propylene and simple olefins

R Wang, Y Wang, R Ding, PB Staub… - Angewandte …, 2023 - Wiley Online Library
Propylene gas is produced worldwide by steam cracking on million‐metric‐ton scale per
year. It serves as a valuable starting material for π‐bond functionalization but is rarely …

Acyclic stereocontrol via allylic organometallic compounds

Y Yamamoto - Accounts of Chemical Research, 1987 - ACS Publications
Conclusion The formal-logical approach is an a priori formulation of necessary structural
requirements incorporated into structures of reactants to perform a bond redis-tribution of a …

Total synthesis of gypsetin, deoxybrevianamide E, brevianamide E, and tryprostatin B: Novel constructions of 2, 3-disubstituted indoles

JM Schkeryantz, JCG Woo, P Siliphaivanh… - Journal of the …, 1999 - ACS Publications
A concise and efficient total synthesis of the acyl-CoA: cholesterol acyltransferase inhibitor
gypsetin (1) is described. The route features a straightforward method for the introduction of …

Development of a highly α-regioselective metal-mediated allylation reaction in aqueous media: new mechanistic proposal for the origin of α-homoallylic alcohols

KT Tan, SS Chng, HS Cheng… - Journal of the American …, 2003 - ACS Publications
This paper described a general method to obtain α-adduct homoallylic alcohols using
indium, zinc, and tin in water. A new mechanism was proposed to account for the formation …

Chiral allylic and allenic metal reagents for organic synthesis

JA Marshall - The Journal of Organic Chemistry, 2007 - ACS Publications
Chiral Allylic and Allenic Metal Reagents for Organic Synthesis | The Journal of Organic
Chemistry ACS ACS Publications C&EN CAS Find my institution Log In The Journal of …

Stereoselective Syntheses of Building Blocks with Three Consecutive Stereogenic Centers: Important Precursors of Polyketide Natural Products [New Synthetic …

RW Hoffmann - Angewandte Chemie International Edition in …, 1987 - Wiley Online Library
Sequences of directly adjacent stereogenic centers were first discovered for the
monosaccharides, which therefore constituted the first focus of interest in Stereoselective …

The total synthesis of avermectin A1a

SJ Danishefsky, DM Armistead, FE Wincott… - Journal of the …, 1989 - ACS Publications
Key fragments for the total synthesis of the title compound were elaborated from D-ribose
and D-glucose and coupled through a crossed aldol dehydration maneuver(33+ 44—» 46) …

Selective allylation of carbonyl compounds in aqueous media

C Einhorn, JL Luche - Journal of organometallic chemistry, 1987 - Elsevier
SELECTIVE ALLYLATION OF CARBONYL COMF’OUNDS IN AQUEOUS MEDIA The use of
aqueous neutral media leads to excellent yields of hom Page 1 177 Journal of Organometallic …