Engineering polymer glue towards 90% zinc utilization for 1000 hours to make high‐performance Zn‐ion batteries

Y Jiao, F Li, X Jin, Q Lei, L Li, L Wang… - Advanced Functional …, 2021 - Wiley Online Library
Zinc (Zn) metal is considered the promising anode for “post‐lithium” energy storage due to
its high volumetric capacity, low redox potential, abundant reserve, and low cost. However …

Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways

Y Wang, CJ Zanelotti, X Wang, R Kerr, L Jin, WH Kan… - Nature Materials, 2021 - nature.com
A critical challenge for next-generation lithium-based batteries lies in development of
electrolytes that enable thermal safety along with the use of high-energy-density electrodes …

100th anniversary of macromolecular science viewpoint: Block copolymers with tethered acid groups: Challenges and opportunities

S Kang, MJ Park - ACS Macro Letters, 2020 - ACS Publications
Scientific research on advanced polymer electrolytes has led to the emergence of all-solid-
state energy storage/transfer systems. Early research began with acid-tethered polymers …

Room temperature to 150° C lithium metal batteries enabled by a rigid molecular ionic composite electrolyte

D Yu, X Pan, JE Bostwick, CJ Zanelotti… - Advanced Energy …, 2021 - Wiley Online Library
Molecular ionic composites (MICs), made from ionic liquids and a rigid‐rod polymer poly (2,
2′‐disulfonyl‐4, 4′‐benzidine terephthalamide)(PBDT), are a new type of rigid gel …

Role of Intradomain Heterogeneity on Ion and Polymer Dynamics in Block Polymer Electrolytes: Investigating Interfacial Mobility and Ion-Specific Dynamics and …

NF Pietra, AG Korovich, PM Ketkar, TH Epps III… - …, 2023 - ACS Publications
Block polymers show promise as solid-state battery electrolytes due to the optimization of
conductive and mechanical properties enabled via tuning of the block chemistry and length …

Broadband dielectric spectroscopy and its application in polymeric materials

I Popov, S Cheng, AP Sokolov - … Engineering: From Precise …, 2022 - Wiley Online Library
Relaxation processes in polymeric systems span over an extremely wide range of time
scales. There are a few experimental techniques capable of covering such a range, and one …

Collective Ion Dynamics in Ionic Plastic Crystals: The Origin of Conductivity Suppression

I Popov, H Zhu, A Khamzin, C Zanelotti… - The Journal of …, 2023 - ACS Publications
Organic ionic plastic crystals (OIPCs) appear as promising materials to replace traditional
liquid electrolytes, especially for use in solid-state batteries. However, OIPCs show low …

Mechanically and Thermally Robust Gel Electrolytes Built from A Charged Double Helical Polymer

D Yu, J Min, F Lin, LA Madsen - Advanced Materials, 2024 - Wiley Online Library
Polymer electrolytes have received tremendous interest in the development of solid‐state
batteries, but often fall short in one or more key properties required for practical applications …

Ionic interactions control the modulus and mechanical properties of molecular ionic composite electrolytes

JE Bostwick, CJ Zanelotti, D Yu, NF Pietra… - Journal of Materials …, 2022 - pubs.rsc.org
Molecular ionic composites (MICs) are a new class of solid electrolytes that combine ionic
liquids (ILs) and a rigid-rod double helical polyelectrolyte, poly (2, 2′-disulfonyl-4, 4 …

Solid-state rigid polymer composite electrolytes with in-situ formed nano-crystalline lithium ion pathways for lithium-metal batteries

Z Wei, J Huang, Z Liao, A Hu, Z Zhang, A Orita… - Energy Storage …, 2024 - Elsevier
Polymer-based solid-state electrolytes with excellent processability and flexibility are ideal
candidates for commercialisation in lithium-metal batteries. However, the current polymer …