Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

Biopolymers such as DNA store information in their chains using controlled sequences of
monomers. Here we describe a non-natural information-containing macromolecule that can …

The strength of multi-scale modeling to support the fundamental understanding and design
of radical polymerization processes is illustrated, considering both controlled and free …

Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a
lot of investigations have focused on the kinetics of this process. During the last decade …

The materials of future depend a lot on properties that are due to “non stable” molecules.
Hence, Dynamic Covalent Bonds (DCB) are covalent bonds that are labile under specific …

A new alkoxyamine (methyl 2-((4-benzoylphenyl)((1-methoxy-2-methyl-1-oxopropan-2-yl)
oxy) amino)-2-methylpropanoate 4) bearing a chromophore group directly linked to the …

In nitroxide-mediated polymerization, NMP, the role of the initiation and therefore the role of
the initiating dissociation rate constant k d1 on the control and livingness of a styrene and n …

Bulk methyl methacrylate (MMA) controlled radical polymerization was carried out using two
2, 2-diphenyl-3-phenylimino-2, 3-dihydroindol-1-yloxyl nitroxide (DPAIO) based …