Coordination geometry in metallo-supramolecular polymer networks

B Hosseinzadeh, M Ahmadi - Coordination Chemistry Reviews, 2022 - Elsevier
Nature employs a wide library of transient interaction to operate adaptively on various time
and length scales. Inspired by such elegant designs, combinations of different …

Recent progress and future challenges in the supramolecular polymerization of metal-containing monomers

N Bäumer, J Matern, G Fernández - Chemical Science, 2021 - pubs.rsc.org
The self-assembly of discrete molecular entities into functional nanomaterials has become a
major research area in the past decades. The library of investigated compounds has …

Bioinspired crowding directs supramolecular polymerisation

N Bäumer, E Castellanos, B Soberats… - Nature …, 2023 - nature.com
Crowding effects are crucial to maintaining functionality in biological systems, but little is
known about their role in analogous artificial counterparts. Within the growing field of …

Luminescence and Length Control in Nonchelated d8‐Metallosupramolecular Polymers through Metal‐Metal Interactions

J Matern, I Maisuls, CA Strassert… - Angewandte Chemie …, 2022 - Wiley Online Library
Supramolecular polymers (SPs) of d8 transition metal complexes have received
considerable attention by virtue of their rich photophysical properties arising from metal …

Visualizing molecular weights differences in supramolecular polymers

Q Li, H Zhang, K Lou, Y Yang, X Ji… - Proceedings of the …, 2022 - National Acad Sciences
Issues of molecular weight determination have been central to the development of
supramolecular polymer chemistry. Whereas relationships between concentration and …

Impact of hydrophobic/hydrophilic balance on aggregation pathways, morphologies, and excited-state dynamics of amphiphilic diketopyrrolopyrrole dyes in aqueous …

N Fukaya, S Ogi, H Sotome, KJ Fujimoto… - Journal of the …, 2022 - ACS Publications
We report the thermodynamic and kinetic aqueous self-assembly of a series of amide-
functionalized dithienyldiketopyrrolopyrroles (TDPPs) that bear various hydrophilic …

Stereomutation and chiroptical bias in the kinetically controlled supramolecular polymerization of cyano-luminogens

L López-Gandul, C Naranjo, C Sánchez… - Chemical …, 2022 - pubs.rsc.org
The synthesis of two pairs of enantiomeric cyano-luminogens 1 and 2, in which the central
chromophore is a p-phenylene or a 2, 5-dithienylbenzene moiety, respectively, is described …

Multi-chiral materials comprising metallosupramolecular and covalent helical polymers containing five axial motifs within a helix

F Rey-Tarrío, E Quiñoá, G Fernández… - Nature Communications, 2023 - nature.com
Supramolecular and covalent polymers share multiple structural effects such as
communication mechanisms among monomer repeating units, which are related to their …

Controllable 1D, 2D and 3D supramolecular assemblies of Ir (iii) complexes

Y Lin, Y Chen, R Cai, H Zhang, C Liu - Materials Chemistry Frontiers, 2023 - pubs.rsc.org
Due to the rich variety of structural motifs, the fabrication of size-controllable two-
dimensional (2D) and three-dimensional (3D) supramolecular assemblies of small …

Metallo‐Supramolecular Helical Fibres from Chiral Phenylacetylene Monomers: Cation Induced Self‐Assembly

F Rey‐Tarrío, S Simón‐Fuente, JM Cuerva… - Angewandte …, 2024 - Wiley Online Library
Chiral metallo‐supramolecular fibres can be easily obtained by mixing a chloroform solution
of a phenylacetylene monomer (PA) that bears a chiral sulfoxide group as pendant, with …