Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII

N Sinha, OS Wenger - Journal of the American Chemical Society, 2023 - ACS Publications
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …

Ligand‐to‐metal charge transfer (LMCT) photochemistry at 3d‐metal complexes: an emerging tool for sustainable organic synthesis

F Juliá - ChemCatChem, 2022 - Wiley Online Library
Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

Luminescent and photofunctional transition metal complexes: From molecular design to diagnostic and therapeutic applications

LCC Lee, KKW Lo - Journal of the American Chemical Society, 2022 - ACS Publications
There has been emerging interest in the exploitation of the photophysical and
photochemical properties of transition metal complexes for diagnostic and therapeutic …

Exploiting the Marcus inverted region for first-row transition metal–based photoredox catalysis

AY Chan, A Ghosh, JT Yarranton, J Twilton, J Jin… - Science, 2023 - science.org
Second-and third-row transition metal complexes are widely employed in photocatalysis,
whereas earth-abundant first-row transition metals have found only limited use because of …

Luminescent first-row transition metal complexes

C Wegeberg, OS Wenger - Jacs Au, 2021 - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …

Multi‐photon excitation in photoredox catalysis: concepts, applications, methods

F Glaser, C Kerzig, OS Wenger - … Chemie International Edition, 2020 - Wiley Online Library
The energy of visible photons and the accessible redox potentials of common photocatalysts
set thermodynamic limits to photochemical reactions that can be driven by traditional visible …

Photoactive complexes with earth-abundant metals

OS Wenger - Journal of the American Chemical Society, 2018 - ACS Publications
In this invited Perspective, recent developments and possible future directions of research
on photoactive coordination compounds made from nonprecious transition metal elements …

Manganese(i) complexes with metal-to-ligand charge transfer luminescence and photoreactivity

P Herr, C Kerzig, CB Larsen, D Häussinger… - Nature Chemistry, 2021 - nature.com
Precious metal complexes with the d 6 valence electron configuration often exhibit
luminescent metal-to-ligand charge transfer (MLCT) excited states, which form the basis for …

Accessing photoredox transformations with an iron (III) photosensitizer and green light

A Aydogan, RE Bangle, A Cadranel… - Journal of the …, 2021 - ACS Publications
Efficient excited-state electron transfer between an iron (III) photosensitizer and organic
electron donors was realized with green light irradiation. This advance was enabled by the …

Charge-transfer processes in metal complexes enable luminescence and memory functions

VWW Yam, AKW Chan, EYH Hong - Nature Reviews Chemistry, 2020 - nature.com
Molecular transition-metal–ligand complexes are emerging as useful paradigms in materials
science. Transition metal complexes have diverse metal d electron configurations, oxidation …