Bio-based polyether from limonene oxide catalytic ROP as green polymeric plasticizer for PLA

V Sessini, M Palenzuela, J Damian, MEG Mosquera - Polymer, 2020 - Elsevier
In this work, the polymerization of Limonene Oxide (LO) has been achieved using an Earth
abundant metal-based catalyst developed in our group, that is very active in ring opening …

Cycloaliphatic epoxidized ionic liquids as new versatile monomers for the development of shape memory PIL networks by 3D printing

AV Radchenko, J Duchet-Rumeau, JF Gérard… - Polymer …, 2020 - pubs.rsc.org
An efficient access to Cycloaliphatic Epoxy-Functionalized Ionic Liquids (CEILs) containing
one or two imidazolium units was described for the first time. Due to the flexibility/versatility …

Simple yttrium salts as highly active and controlled catalysts for the atom-efficient synthesis of high molecular weight polyesters

ZA Wood, MK Assefa, ME Fieser - Chemical Science, 2022 - pubs.rsc.org
The ring-opening copolymerization (ROCOP) of epoxides and cyclic anhydrides is a
promising route to sustainable aliphatic polyesters with diverse mechanical and thermal …

Ring-opening copolymerization of cyclic epoxide and anhydride using a five-coordinate chromium complex with a sterically demanding amino triphenolate ligand

HK Ryu, DY Bae, H Lim, E Lee, K Son - Polymer Chemistry, 2020 - pubs.rsc.org
An alternating ring-opening copolymerization (ROCOP) of epoxides (cyclohexene oxide,
limonene oxide) and anhydrides (phthalic anhydride, naphthalic anhydride and maleic …

Chromium amino-bis (phenolate) complexes as catalysts for ring-opening polymerization of cyclohexene oxide

K Ambrose, JN Murphy, CM Kozak - Macromolecules, 2019 - ACS Publications
The chromium (III) amino-bis (phenolate)“ate” complex,{Na [CrCl2 L1]}, 1, where L1= 6, 6′-
((1, 4-diazepane-1, 4-diyl) bis (methylene)) bis (2, 4-di-tert-butylphenolato) and its …

BODIPY-based photoacid generators for light-induced cationic polymerization

K Sambath, Z Wan, Q Wang, H Chen, Y Zhang - Organic letters, 2020 - ACS Publications
Photoacid generators (PAGs) are organic compounds that can generate protons (H+) upon
irradiation with certain wavelengths of light. In this work, we designed and synthesized the …

Epoxy resins and composites from epoxidized linseed oil copolymers with cyclohexene oxide

ZS Petrović, J Hong, ML Vuković, J Djonlagić - Biocatalysis and Agricultural …, 2022 - Elsevier
New materials were made by copolymerization of epoxidized linseed oil (ELO) and
cyclohexene oxide (CHO) catalyzed by tris (pentafluorophenyl) borane (BCF). Pure …

Poly (cyclohexene oxide)/clay nanocomposites by photoinitiated cationic polymerization via activated monomer mechanism

A Oral, MA Tasdelen, AL Demirel… - Journal of Polymer …, 2009 - Wiley Online Library
Abstract Poly (cyclohexene oxide)(PCHO)/clay nanocomposites were prepared by in situ
photoinitiated activated monomer cationic polymerization. The polymerization of …

Living Cationic Ring-Opening Homo-and Copolymerization of Cyclohexene Oxide by “Dormant” Species Generation Using Cyclic Ethers as Lewis Basic Additives

M Inoue, A Kanazawa, S Aoshima - Macromolecules, 2021 - ACS Publications
The living cationic ring-opening polymerization of cyclohexene oxide (CHO) was
demonstrated to proceed using cyclic ethers as Lewis basic additives that potentially form …

Metal‐Free Ring‐Opening Alternating Copolymerization of Epoxides and Cyclic Anhydrides Mediated by a Ternary Phosphazene Base and Carboxylic Acids

X Kou, Y Li, Y Shen, Z Li - Macromolecular Chemistry and …, 2019 - Wiley Online Library
Organocatalytic, metal‐free ring‐opening alternating copolymerization (ROAP) of epoxides
and cyclic anhydrides to produce polyesters with well‐defined alternating structure remains …