Gold catalysed regio-and chemoselective azo coupling of 1, 2-and 1, 4-diazoquinones with 1 H-indoles

J Jin, AFL Rojas, Y Zhao, SH Kyne, B Xia… - Organic Chemistry …, 2024 - pubs.rsc.org
A synthetic method to prepare (E)-3-arylazoindoles efficiently that relies on the gold (I)-
catalysed azo coupling of 1, 2-and 1, 4-diazoquinones with 1H-indoles under mild reaction …

Engineering a photothermal responsive cellulose carbon capture material for solar-driven CO2 desorption

W Luo, W Lu, Q Xiang, L Zhan, X Yang, H Jiang… - Chemical Engineering …, 2024 - Elsevier
The utilization of the solar-driven CO 2 desorption of carbon capture materials opens a
promising avenue to reduce energy consumption in the carbon capture process. A crucial …

Denitrogenative dismantling of heteroaromatics by nucleophilic substitution reactions with diazomethyl compounds

S Biswas, C Empel, LM Sanchez-Palestino… - Chemical …, 2024 - pubs.rsc.org
Nucleophiles from deprotonation of diazomethyl compounds having diverse electron
withdrawing groups react with 4-carboxylato-1, 2, 3-triazines at the 6-position to extrude …

The “cesium effect” magnified: exceptional chemoselectivity in cesium ion mediated nucleophilic reactions

S Biswas, WB Hughes, L De Angelis, GC Haug… - Chemical …, 2024 - pubs.rsc.org
Chemodivergent construction of structurally distinct heterocycles from the same precursors
by adjusting specific reaction parameters is an emergent area of organic synthesis; yet …

Strain‐Driven [3+ 2] Cycloaddition of Triazine 1‐Oxides with Arynes/Cyclooctyne: Access to Benzisoxazoles/Cyclooctene‐Fused Isoxazoles

S Biswas, LM Sanchez‐Palestino… - European Journal of …, 2024 - Wiley Online Library
Abstract The 4‐carboxylates of 1, 2, 3‐triazine 1‐oxides undergo [3+ 2] cycloaddition with in
situ generated benzynes and naphthyne and also with cyclooctyne that, following extrusion …

Reactivity of 1, 2, 3-Triazines and the Oxides

D Zhao, L Guo - Synfacts, 2023 - thieme-connect.com
Significance: 1, 2, 3-Triazines are valuable synthons for various N-heterocycles. However,
the reactions of 1, 2, 3-triazines with various nucleophiles are not thoroughly explored or …