The discovery and development of new chemical reactions is a major focus of research
activity in organic chemistry. The chemical synthesis of molecules provided by Nature has …

The unique steric effect of geminal bis (silane)[(R3Si) 2CH] allows an exo-selective
intermolecular Diels–Alder reaction of geminal bis (silyl) dienes with α, β-unsaturated …

The Diels− Alder reactions of a series of silyloxydienes and silylated dienes with acyclic α, β-
unsaturated ketones and N-acyloxazolidinones have been investigated. The endo/exo …

Abstract Asymmetric hetero‐Diels‐Alder (AHDA) reactions provide a multitude of
opportunities for the highly efficient, regio‐and stereoselective construction of various …

The preparation of C 2 symmetric 2, 3-dibenzobicyclo [2.2. 2] octanedione dioxime is
reported. This ligand is then used in the preparation of a (pyridine)(glyoxime) 2cobalt (III) …

At this point in time, a general exo-selective Diels-Alder reaction does not exist and its
development constitutes one of the greatest remaining challenges for this reaction. 2 In …

An exo-selective Diels–Alder (exo-DA) reaction in which the formed diastereomer is different
from that formed in the conventional endo-selective Diels–Alder (endo-DA) reaction was …

The factors controlling the reactivity and exo/endo selectivity of Diels–Alder reactions of
geminal bis (silyl) dienes catalyzed by AlEt2Cl are studied at the B3LYP-D3 (BJ)(SMD …

A new type of cyclic amino-functionalized s-cis boroxyvinylcarbene complex of group 6
metals has been synthesized. These complexes underwent Diels− Alder-type reactions with …

The complex [Os (NH3) 5 (η2-anisole)] 2+ reacts with acetals or Michael acceptors to form 4-
methoxystyrene complexes that are exclusively coordinated at the arene (η2). These styrene …