Rational strategies for proton-conductive metal–organic frameworks

DW Lim, H Kitagawa - Chemical Society Reviews, 2021 - pubs.rsc.org
Since the transition of energy platforms, proton-conducting materials have played a
significant role in broad applications for electrochemical devices. In particular, solid-state …

Proton transport in metal–organic frameworks

DW Lim, H Kitagawa - Chemical reviews, 2020 - ACS Publications
Solid-state proton conductors (SSPCs), which are a key component for the safety and
efficiency of fuel cells, have received much attention due to their broad application in …

Metal–organic frameworks as a versatile platform for proton conductors

Y Ye, L Gong, S Xiang, Z Zhang, B Chen - Advanced Materials, 2020 - Wiley Online Library
Metal–organic frameworks (MOFs) are an intriguing type of crystalline porous materials that
can be readily built from metal ions or clusters and organic linkers. Recently, MOF materials …

A flexible metal–organic framework with a high density of sulfonic acid sites for proton conduction

F Yang, G Xu, Y Dou, B Wang, H Zhang, H Wu, W Zhou… - Nature Energy, 2017 - nature.com
The design of stable electrolyte materials with high proton conductivity for use in proton
exchange membrane fuel cells remains a challenge. Most of the materials explored have …

Precision-engineered construction of proton-conducting metal–organic frameworks

L Zhu, H Yang, T Xu, F Shen, C Si - Nano-Micro Letters, 2025 - Springer
Proton-conducting materials have attracted considerable interest because of their extensive
application in energy storage and conversion devices. Among them, metal–organic …

Superprotonic Conductivity of MOFs and Other Crystalline Platforms Beyond 10−1 S cm−1

SC Pal, MC Das - Advanced Functional Materials, 2021 - Wiley Online Library
The proton‐exchange membrane (PEM) is a fundamental module of proton‐exchange
membrane fuel cells (PEMFCs), permitting proton passage and thus governing the overall …

Metal-organic frameworks: structure, properties, methods of synthesis and characterization

VV Butova, MA Soldatov, AA Guda… - Russian Chemical …, 2016 - iopscience.iop.org
This review deals with key methods of synthesis and characterization of metal-organic
frameworks (MOFs). The modular structure affords a wide variety of MOFs with different …

Brønsted acidity in metal–organic frameworks

J Jiang, OM Yaghi - Chemical reviews, 2015 - ACS Publications
The past 20 years have witnessed rapid development of reticular chemistry, 1, 2 which is
concerned with linking molecular building units with strong chemical bonds to form …

Preparation and applications of metal–organic frameworks composed of sulfonic acid

DK Yoo, G Lee, MMH Mondol, HJ Lee, CM Kim… - Coordination Chemistry …, 2023 - Elsevier
Functionalized metal–organic frameworks (MOFs) attract much attention recently because of
the possible applications in various fields owing to the loaded functionalities. In this review …

Superprotonic conductivity of a UiO‐66 framework functionalized with sulfonic acid groups by facile postsynthetic oxidation

WJ Phang, H Jo, WR Lee, JH Song… - Angewandte Chemie …, 2015 - Wiley Online Library
Facile postsynthetic oxidation of the thiol‐laced UiO‐66‐type framework UiO‐66 (SH) 2
enabled the generation of UiO‐66 (SO3H) 2 with sulfonic acid groups covalently linked to …