Controlling the triplet states and their application in external stimuli-responsive triplet–triplet-annihilation photon upconversion: from the perspective of excited state …

X Xiao, W Tian, M Imran, H Cao, J Zhao - Chemical Society Reviews, 2021 - pubs.rsc.org
The property of organic light-responsive materials is determined by their electronic excited
states to a large extent, for instance, the radiative decay rate constants, redox potentials, and …

First-principles calculations of excited-state decay rate constants in organic fluorophores

MT do Casal, K Veys, MHE Bousquet… - The Journal of …, 2023 - ACS Publications
In this Perspective, we discuss recent advances made to evaluate from first-principles the
excited-state decay rate constants of organic fluorophores, focusing on the so-called static …

Molecular mechanism of viscosity sensitivity in BODIPY rotors and application to motion-based fluorescent sensors

X Liu, W Chi, Q Qiao, SV Kokate, EP Cabrera, Z Xu… - Acs …, 2020 - ACS Publications
Viscosity in the intracellular microenvironment shows a significant difference in various
organelles and is closely related to cellular processes. Such microviscosity in live cells is …

Extensive analysis of the parameters influencing radiative rates obtained through vibronic calculations

MHE Bousquet, TV Papineau, K Veys… - Journal of Chemical …, 2023 - ACS Publications
Defining a theoretical model systematically delivering accurate ab initio predictions of the
fluorescence quantum yields of organic dyes is highly desirable for designing improved …

Controlling the fluorescence quantum yields of benzothiazole-difluoroborates by optimal substitution

P Rybczyński, MHE Bousquet… - Chemical …, 2022 - pubs.rsc.org
Precise tuning of the fluorescence quantum yield, vital for countless applications of
fluorophores, remains exceptionally challenging due to numerous factors affecting energy …

Toward prediction of nonradiative decay pathways in organic compounds II: Two internal conversion channels in BODIPYs

Z Lin, AW Kohn, T Van Voorhis - The Journal of Physical …, 2020 - ACS Publications
Boron-dipyrromethene (BODIPY) molecules are widely used as laser dyes and have
therefore become a popular research topic within recent years. Numerous studies have …

Transforming Dyes into Fluorophores: Exciton‐Induced Emission with Chain‐like Oligo‐BODIPY Superstructures

LJ Patalag, J Hoche, R Mitric, DB Werz… - Angewandte …, 2022 - Wiley Online Library
Herein we present a systematic study demonstrating to which extent exciton formation can
amplify fluorescence based on a series of ethylene‐bridged oligo‐BODIPYs. A set of non …

Different quenching effect of intramolecular rotation on the singlet and triplet excited states of Bodipy

Z Lou, Y Hou, K Chen, J Zhao, S Ji… - The Journal of …, 2018 - ACS Publications
It is well-known that the fluorescence of a chromophore can be efficiently quenched by the
free rotor effect, sometimes called intramolecular rotation (IMR), ie by a large-amplitude …

Flapping viscosity probe that shows polarity-independent ratiometric fluorescence

R Kotani, H Sotome, H Okajima, S Yokoyama… - Journal of Materials …, 2017 - pubs.rsc.org
A variety of fluorescent molecular viscosity probes have been widely used for mapping the
local viscosity in cells and for monitoring the microenvironments in materials. However, their …

Molecular design of near-infrared fluorescent Pdots for tumor targeting: aggregation-induced emission versus anti-aggregation-caused quenching

WK Tsai, CI Wang, CH Liao, CN Yao, TJ Kuo… - Chemical …, 2019 - pubs.rsc.org
Semiconducting polymer dots (Pdots) have recently emerged as a new type of ultrabright
fluorescent probe that has been proved to be very useful for biomedical imaging. However …