In this article, the effects of size and confinement at the nanometre size scale on both the melting temperature, T m, and the glass transition temperature, T g, are reviewed. Although …
We present a review of experimental, theoretical, and molecular simulation studies of confinement effects on freezing and melting. We consider both simple and more complex …
J Baschnagel, F Varnik - Journal of Physics: Condensed Matter, 2005 - iopscience.iop.org
We survey results of computer simulations for the structure and dynamics of supercooled polymer melts and films. Our survey is mainly concerned with features of a coarse grained …
R Richert - Annual review of physical chemistry, 2011 - annualreviews.org
Near their glass transition temperature T g, supercooled liquids display dramatic changes regarding the dynamics if subject to geometrical restrictions on the scale of 2 to 200 nm …
T Azaïs, C Tourné-Péteilh, F Aussenac… - Chemistry of …, 2006 - ACS Publications
Ibuprofen (an anti-inflammatory drug that is a crystalline solid at ambient temperature) has been encapsulated in MCM-41 silica matrices with different pore diameters (35 and 116 Å) …
W Zheng, A Mohammed, LG Hines Jr… - The Journal of …, 2011 - ACS Publications
In this paper, the morphology and bulk physical properties of 1, 3-dialkylimidazolium bis {(trifluoromethane) sulfonyl} amide ([(CN/2) 2im][NTf2]) are compared to that of 1-alkyl-3 …
P Scheidler, W Kob, K Binder - The Journal of Physical Chemistry …, 2004 - ACS Publications
We present the results of molecular dynamics computer simulations of a binary Lennard- Jones liquid confined between two parallel rough walls. These walls are realized by frozen …
KW Desmond, ER Weeks - Physical Review E—Statistical, Nonlinear, and Soft …, 2009 - APS
Studies of random close packing of spheres have advanced our knowledge about the structure of systems such as liquids, glasses, emulsions, granular media, and amorphous …
We relate the dynamical behavior of molecular liquids confined in mesoscopic cylindrical pores to the thermodynamic properties, heat capacity and density and to the static structure …