The physics of the colloidal glass transition

GL Hunter, ER Weeks - Reports on progress in physics, 2012 - iopscience.iop.org
As one increases the concentration of a colloidal suspension, the system exhibits a dramatic
increase in viscosity. Beyond a certain concentration, the system is said to be a colloidal …

Effects of confinement on material behaviour at the nanometre size scale

M Alcoutlabi, GB McKenna - Journal of Physics: Condensed …, 2005 - iopscience.iop.org
In this article, the effects of size and confinement at the nanometre size scale on both the
melting temperature, T m, and the glass transition temperature, T g, are reviewed. Although …

Effects of confinement on freezing and melting

C Alba-Simionesco, B Coasne, G Dosseh… - Journal of Physics …, 2006 - iopscience.iop.org
We present a review of experimental, theoretical, and molecular simulation studies of
confinement effects on freezing and melting. We consider both simple and more complex …

Computer simulations of supercooled polymer melts in the bulk and in confined geometry

J Baschnagel, F Varnik - Journal of Physics: Condensed Matter, 2005 - iopscience.iop.org
We survey results of computer simulations for the structure and dynamics of supercooled
polymer melts and films. Our survey is mainly concerned with features of a coarse grained …

Dynamics of nanoconfined supercooled liquids

R Richert - Annual review of physical chemistry, 2011 - annualreviews.org
Near their glass transition temperature T g, supercooled liquids display dramatic changes
regarding the dynamics if subject to geometrical restrictions on the scale of 2 to 200 nm …

Solid-state NMR study of ibuprofen confined in MCM-41 material

T Azaïs, C Tourné-Péteilh, F Aussenac… - Chemistry of …, 2006 - ACS Publications
Ibuprofen (an anti-inflammatory drug that is a crystalline solid at ambient temperature) has
been encapsulated in MCM-41 silica matrices with different pore diameters (35 and 116 Å) …

Effect of cation symmetry on the morphology and physicochemical properties of imidazolium ionic liquids

W Zheng, A Mohammed, LG Hines Jr… - The Journal of …, 2011 - ACS Publications
In this paper, the morphology and bulk physical properties of 1, 3-dialkylimidazolium bis
{(trifluoromethane) sulfonyl} amide ([(CN/2) 2im][NTf2]) are compared to that of 1-alkyl-3 …

The relaxation dynamics of a supercooled liquid confined by rough walls

P Scheidler, W Kob, K Binder - The Journal of Physical Chemistry …, 2004 - ACS Publications
We present the results of molecular dynamics computer simulations of a binary Lennard-
Jones liquid confined between two parallel rough walls. These walls are realized by frozen …

Random close packing of disks and spheres in confined geometries

KW Desmond, ER Weeks - Physical Review E—Statistical, Nonlinear, and Soft …, 2009 - APS
Studies of random close packing of spheres have advanced our knowledge about the
structure of systems such as liquids, glasses, emulsions, granular media, and amorphous …

Confinement of molecular liquids: Consequences on thermodynamic, static and dynamical properties of benzene and toluene

C Alba-Simionesco, G Dosseh, E Dumont… - The European Physical …, 2003 - Springer
We relate the dynamical behavior of molecular liquids confined in mesoscopic cylindrical
pores to the thermodynamic properties, heat capacity and density and to the static structure …