Reactive p-block cations stabilized by weakly coordinating anions

TA Engesser, MR Lichtenthaler, M Schleep… - Chemical Society …, 2016 - pubs.rsc.org
The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …

Recent advances in bismuth activated photonic materials

HT Sun, J Zhou, J Qiu - Progress in Materials Science, 2014 - Elsevier
Bismuth is one of the most thoroughly investigated main group elements, which has been
regarded as 'the wonder metal'because of its diverse oxidation states and profound …

NaAlCl4: New Halide Solid Electrolyte for 3 V Stable Cost-Effective All-Solid-State Na-Ion Batteries

J Park, JP Son, W Ko, JS Kim, Y Choi, H Kim… - ACS Energy …, 2022 - ACS Publications
Although high-voltage-stable halide solid electrolytes (SEs) have emerged, only a few Na+
halide SEs have been developed thus far. Moreover, the use of expensive elements reduces …

Halometallate ionic liquids–revisited

J Estager, JD Holbrey… - Chemical Society Reviews, 2014 - pubs.rsc.org
Ionic liquids with chlorometallate anions may not have been the first ionic liquids, however, it
was their development that lead to the recognition that ionic liquids are a distinct, and useful …

Ionic liquids: new perspectives for inorganic synthesis?

D Freudenmann, S Wolf, M Wolff… - Angewandte Chemie …, 2011 - Wiley Online Library
Ionic liquids are credited with a number of unusual properties. These include a low vapor
pressure, a wide liquid‐phase range, weakly coordinating properties, and a high …

Lewis acidic ionic liquids

LC Brown, JM Hogg, M Swadźba-Kwaśny - Ionic Liquids II, 2018 - Springer
Until very recently, the term Lewis acidic ionic liquids (ILs) was nearly synonymous with
halometallate ILs, with a strong focus on chloroaluminate (III) systems. The first part of this …

Ionic liquids as crystallisation media for inorganic materials

E Ahmed, J Breternitz, MF Groh, M Ruck - CrystEngComm, 2012 - pubs.rsc.org
Ionic liquids (ILs) have made a great impact on materials science and are being explored for
potential applications in several disciplines. In this article, we briefly highlight the current …

Ionic Liquids and Poly (ionic liquid) s for Morphosynthesis of Inorganic Materials

MR Gao, J Yuan, M Antonietti - Chemistry–A European Journal, 2017 - Wiley Online Library
Ionic liquids (ILs) are new, innovative ionic solvents with rich physicochemical properties
and intriguing pre‐organized solvent structures; these materials offer great potential to …

Atom hybridization of metallic elements: Emergence of subnano metallurgy for the post-nanotechnology

T Imaoka, A Kuzume, M Tanabe, T Tsukamoto… - Coordination Chemistry …, 2023 - Elsevier
Miniaturizing metallic materials from the nanoscale to the atomic scale transforms the
structures and physical properties. Among these sub-nanoscale materials, some catalysts …

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn= N, P, As)

K Oberdorf, A Hanft, J Ramler… - Angewandte Chemie …, 2021 - Wiley Online Library
The controlled release of well‐defined radical species under mild conditions for subsequent
use in selective reactions is an important and challenging task in synthetic chemistry. We …