Abstract Organic peroxy radicals (RO 2), formed from the degradation of hydrocarbons and
other volatile organic compounds (VOCs), play a key role in tropospheric oxidation …

The chemistry of nitrated alkoxy radicals, and its impact on RO2 measurements using the
laser induced fluorescence (LIF) technique, is examined by a combined theoretical and …

This work entails a detailed modeling and experimental study for the oxidation kinetics of
acetaldehyde (CH3CHO) and its interaction with NO x. The ignition behavior of …

Absolute line strengths of several transitions in the ν 1 fundamental band of the hydroxyl
radical (OH) have been measured by simultaneous determination of hydrogen peroxide (H 2 …

The temperature-dependent kinetic parameters, branching fractions, and chaperone effects
of the self-and cross-reactions between acetonyl peroxy (CH3C (O) CH2O2) and hydro …

The rate constant for the self-reaction of the acetonyl peroxy radicals, CH3C (O) CH2O2, has
been determined using laser photolysis/continuous wave cavity ring down spectroscopy (cw …

Quantitative determination of multiple transient species is critical in investigating reaction
mechanisms and kinetics under various conditions. Dual-comb spectroscopy, a comb-laser …

The self-reaction of acetylperoxy radicals (CH3C (O) O2•)(R1) as well as their reaction with
methyl peroxy radicals (CH3O2•)(R2) have been studied using laser photolysis coupled to a …

Pulsed laser photolysis coupled with infrared (IR) wavelength modulation spectroscopy and
ultraviolet (UV) absorption spectroscopy was used to study the kinetics and branching …

The energetics, thermochemistry and kinetics for the reaction between n-butyl peroxy radical
and HO 2 radical was computed using CCSD (T)/aug-cc-pVDZ//B3LYP/6-311G (d, p) level of …