The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry

A Escuer, J Esteban, SP Perlepes… - Coordination Chemistry …, 2014 - Elsevier
The chemistry of the azido-bridged coordination clusters continues to attract the intense
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …

Inducing Single-Molecule Magnetism in a Family of Loop-of-Loops Aggregates: Heterometallic Mn40Na4 Clusters and the Homometallic Mn44 Analogue

EE Moushi, C Lampropoulos… - Journal of the …, 2010 - ACS Publications
The syntheses, crystal structures, and magnetic properties of a new family of heterometallic
Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of …

Comproportionation reactions to manganese (III/IV) pivalate clusters: a new half-integer spin single-molecule magnet

S Mukherjee, KA Abboud, W Wernsdorfer… - Inorganic …, 2013 - ACS Publications
The comproportionation reaction between MnII and MnVII reagents under acidic conditions
has been investigated in the presence of pivalic acid as a route to new high oxidation state …

A Mn15 single-molecule magnet consisting of a supertetrahedron incorporated in a loop

EE Moushi, A Masello, W Wernsdorfer… - Dalton …, 2010 - pubs.rsc.org
Two new Mn15 clusters consisting of a supertetrahedron which is incorporated in a loop are
reported. The reactions of [Mn (O2CEt) 2]· 2H2O with the diols 1, 3-propanediol (H2pd) or 2 …

Studies of magnetic properties and HFEPR of octanuclear manganese single-molecule magnets

CC Wu, S Datta, W Wernsdorfer, GH Lee, S Hill… - Dalton …, 2010 - pubs.rsc.org
A new octanuclear manganese cluster [Mn8 (Hpmide) 4O4 (EtCOO) 6](ClO4) 2 (1) is
achieved by employing Hpmide as the ligand, and this paper examines the synthesis, X-ray …

Using the flexible ligand bis (2-hydroxyethyl) amino–tris (hydroxymethyl) methane (“bis–tris”) to access a family of 3d–4f Mn III 4 Ln 4 complexes

A Khan, Y Lan, GE Kostakis, CE Anson… - Dalton Transactions, 2012 - pubs.rsc.org
A series of isostructural 3d–4f coordination clusters (CCs)[Mn4Ln4 (OH) 6 (H2L) 2 (H3L) 2
(PhCO2) 2 (N3) 2 (MeOH) 4] Cl1. 6 (N3) 0.4 (NO3) 2· 2.4 H2O· 1.6 MeOH where Ln= Gd, Tb …

Pentanuclear complexes with unusual structural topologies from the initial use of two aliphatic amino-alcohol ligands in Fe chemistry

CM Kizas, MJ Manos, V Nastopoulos… - Dalton …, 2012 - pubs.rsc.org
Five novel pentanuclear Fe3+ clusters with the aliphatic amino-alcohol ligands 3-amino-1-
propanol (Hap) and 2-(hydroxymethyl) piperidine (Hhmpip)[Fe5 (μ3-Ο) 2 (L) 4 (O2CR) 7][L …

22-Azametallacrown-8 complex with a triazole-bridged ligand: synthesis, structure and magnetic properties

H Yang, QX Yao, YW Li, DC Li, JM Dou - Dalton Transactions, 2014 - pubs.rsc.org
Reaction of Mn (OAc) 2· 4H2O with the H2L ligand affords a new manganese 22-MC-8
azametallacrown [Mn8 (μ3-O) 2 (μ3-OH) 2 (μ2-OH) 2 (L) 6 (OAc) 2 (OH2) 4]· 2DMF (H2L= 3 …

Heterometallic FeIII–CeIV complexes from the use of aliphatic aminoalcohol ligands

CM Kizas, C Papatriantafyllopoulou, MJ Manos… - Polyhedron, 2013 - Elsevier
Six novel heteronuclear FeIII/CeIV clusters with the ligands 3-amino-1-propanol (Hap) and 2-
(hydroxymethyl) piperidine (Hhmpip)[FeIII4CeIV6O8 (L) 4 ((CH3) 3CCO2) 12 (RCO2) 4](R …

Hexanuclear complexes from the use of a series of amino-alcohol ligands in Fe chemistry

C Papatriantafyllopoulou, CM Kizas, MJ Manos… - Polyhedron, 2013 - Elsevier
Eight novel Fe III 6 clusters with the amino-alcohol ligands 3-amino-1-propanol (apH), N-
hydroxyethylpiperidine (N-hepipH), 2-hydroxyethylpiperidine (2-hepipH), 2 …