Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Palladium alloys used as electrocatalysts for the oxygen reduction reaction

T Wang, A Chutia, DJL Brett, PR Shearing… - Energy & …, 2021 - pubs.rsc.org
Palladium-based alloy materials as cathodes for the reduction of oxygen are regarded as
potential substitutes for platinum-based catalysts in fuel cells. In this work, we present a …

Understanding catalytic activity trends in the oxygen reduction reaction

A Kulkarni, S Siahrostami, A Patel… - Chemical reviews, 2018 - ACS Publications
Despite the dedicated search for novel catalysts for fuel cell applications, the intrinsic
oxygen reduction reaction (ORR) activity of materials has not improved significantly over the …

Modulating electronic structures of inorganic nanomaterials for efficient electrocatalytic water splitting

X Du, J Huang, J Zhang, Y Yan, C Wu… - Angewandte Chemie …, 2019 - Wiley Online Library
Electrocatalytic water splitting is one of the most promising sustainable energy conversion
technologies, but is limited by the sluggish electrochemical reactions. Inorganic …

Charge-redistribution-enhanced nanocrystalline Ru@ IrOx electrocatalysts for oxygen evolution in acidic media

J Shan, C Guo, Y Zhu, S Chen, L Song, M Jaroniec… - Chem, 2019 - cell.com
Achieving high activity and long-term stability is a major challenge in the design of catalysts.
In particular, the oxygen evolution reaction (OER) in acidic media, which plays a key role in …

Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction

Y Nie, L Li, Z Wei - Chemical Society Reviews, 2015 - pubs.rsc.org
Developing highly efficient catalysts for the oxygen reduction reaction (ORR) is key to the
fabrication of commercially viable fuel cell devices and metal–air batteries for future energy …

Core–shell nanoparticles: synthesis and applications in catalysis and electrocatalysis

MB Gawande, A Goswami, T Asefa, H Guo… - Chemical Society …, 2015 - pubs.rsc.org
Core–shell nanoparticles (CSNs) are a class of nanostructured materials that have recently
received increased attention owing to their interesting properties and broad range of …

Tuning nanoparticle structure and surface strain for catalysis optimization

S Zhang, X Zhang, G Jiang, H Zhu, S Guo… - Journal of the …, 2014 - ACS Publications
Controlling nanoparticle (NP) surface strain, ie compression (or stretch) of surface atoms, is
an important approach to tune NP surface chemistry and to optimize NP catalysis for …

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst

K Tedsree, T Li, S Jones, CWA Chan, KMK Yu… - Nature …, 2011 - nature.com
Formic acid (HCOOH) has great potential as an in situ source of hydrogen for fuel cells,
because it offers high energy density, is non-toxic and can be safely handled in aqueous …

A Systematic Investigation of p-Nitrophenol Reduction by Bimetallic Dendrimer Encapsulated Nanoparticles

ZD Pozun, SE Rodenbusch, E Keller… - The Journal of …, 2013 - ACS Publications
We demonstrate that the reduction of p-nitrophenol to p-aminophenol by NaBH4 is catalyzed
by both monometallic and bimetallic nanoparticles (NPs). We also demonstrate a …