The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Nucleophilic phosphine catalysis is a practical and powerful tool for the synthesis of various
heterocyclic compounds with the advantages of environmentally friendly, metal-free, and …

Asymmetric radical bicyclization processes have been developed via metalloradical
catalysis (MRC) to stereoselectively construct chiral chromanones and chromanes bearing …

A facile and efficient method to produce optically pure benzofuroindolines, especially those
without 3‐substituents that are susceptible to rearomatization, through [3+ 2] annulation of …

We report a phosphine‐catalyzed ring opening of electron‐deficient
alkylidenecyclopropanes (ACPs) to generate allylic phosphonium zwitterions that resemble …

A novel strategy for the catalyst-free domino cross-olefination and intramolecular cyclization
of Morita–Baylis–Hillman carbonates with sulfur ylides has been established, resulting in the …

The first catalytic enantioselective ring-opening reaction of donor–acceptor cyclopropanes
with water is described. By employing Cy-TOX/Cu (II) as catalyst, the reaction performed …

Polycyclic compounds are widely found in natural products and drug molecules with
important biological activities, which attracted the attention of many chemists. Phosphine …

AP (NMe2) 3-mediated reductive intramolecular cyclopropanation is developed for the first
time, which provides facile access to a wide variety of cyclopropane-fused heterocycles …

3, 4-Enhanced polymerization of isoprene catalyzed by late transition metal with high activity
remains one of the great challenges in synthetic rubber chemistry. Herein, a library of [N, N …