Chemistry of (. mu.-dithio) bis (tricarbonyliron), an inorganic mimic of organic disulfides. 3. Reaction with low-valent metal compounds and some interesting isolobal …
M Cowie, RL DeKock, TR Wagenmaker… - …, 1989 - ACS Publications
The analogy between (M-S2) Fe2 (CO) 6 and organic disulfides extends to reactions with
low-valent metal species. The following zerovalent metal phosphine complexes and …
low-valent metal species. The following zerovalent metal phosphine complexes and …
The making and breaking of carbon-hydrogen bonds on a metal cluster framework. Analysis of the tautomerization and deprotonation of Fe3 (CO) 9CH4 leading to the …
TK Dutta, JC Vites, GB Jacobsen, TP Fehlner - Organometallics, 1987 - ACS Publications
The hydrocarbyl cluster having the composition Fe3 (CO) 9CH4 (I) is shown to exist in
solution as a mixture of three tautomers:(pH) 3Fe3 (CO) 9 (M3-CH), A;(pH) 2Fe3 (CO) 9 (p3 …
solution as a mixture of three tautomers:(pH) 3Fe3 (CO) 9 (M3-CH), A;(pH) 2Fe3 (CO) 9 (p3 …
[HTML][HTML] Metal–metal bonding in bridged ligand systems: experimental and theoretical charge densities in Co3(μ3-CX)(CO)9 (X = H, Cl)
LJ Farrugia, C Evans - Comptes rendus. Chimie, 2005 - comptes-rendus.academie-sciences …
Experimental charge density studies on Co 3 (μ 3-CX)(CO) 9 (1a X= H, 1b X= Cl) have been
undertaken at 100 and 115 K respectively, using Mo Kα X-radiation. The nature of the metal …
undertaken at 100 and 115 K respectively, using Mo Kα X-radiation. The nature of the metal …
The structure and properties of HFe3 (CO) 9BH3R and the conjugate bases [HFe3 (CO) 9BH2R]-(R= H and CH3). Inorganometallic analogs of hydrocarbyltriiron …
J Vites, CE Housecroft, C Eigenbrot… - Journal of the …, 1986 - ACS Publications
The ferraboranes (# tH) Fe3 (CO) 9BH3R and the conjugate bases [(MH) Fe3 (CO) 9BH2R],
R= H and CH3, have been prepared andcharacterized. Crystals of HFe3 (CO) 9BH4 form in …
R= H and CH3, have been prepared andcharacterized. Crystals of HFe3 (CO) 9BH4 form in …
Cluster mimetics. The preparation and characterization of (. mu.-H) Fe3 (CO) 9 (. mu. 3-BH4)
J Vites, C Eigenbrot, TP Fehlner - Journal of the American …, 1984 - ACS Publications
Confirmation of structure and geometrical details of I resulted from a single-crystal X-ray
structure determination14 summarized in Figure 1. The structureconsists of a metal triangle …
structure determination14 summarized in Figure 1. The structureconsists of a metal triangle …
Conversion of an unsaturated metallacycle into a carbon-rich nido-metallacarborane. The BH fragment as a cluster functional group
FE Hong, CW Eigenbrot, TP Fehlner - Journal of the American …, 1989 - ACS Publications
The reaction of the metallacycle Cp (PPh3) CoCPhCPhCPhCPh, 1, with monoboranes
containing at least one BH bond provides a new route to the formation of a Ŧic/o …
containing at least one BH bond provides a new route to the formation of a Ŧic/o …
Molecular structure of gaseous titanium tris (tetrahydroborate), Ti (BH 4) 3: Experimental determination by electron diffraction and molecular orbital analysis of some Ti …
CJ Dain, AJ Downs, MJ Goode, DG Evans… - Journal of the …, 1991 - pubs.rsc.org
The structure of gaseous titanium tris (tetrahydroborate) has been determined by analysis of
the electron diffraction patterns due to the molecules Ti (BH4) 3 and Ti (BD4) 3. The …
the electron diffraction patterns due to the molecules Ti (BH4) 3 and Ti (BD4) 3. The …
Electron distribution and bonding in. Eta. 3-cyclopropenyl-metal complexes
DL Lichtenberger, ML Hoppe, L Subramanian… - …, 1993 - ACS Publications
Metallacyclobutadienes 1 and^-cyclopropenyl metal complexes 2 are both possible
intermediates in alkyne metathesis reactions.* 1 2One mechanism of metathesis involves …
intermediates in alkyne metathesis reactions.* 1 2One mechanism of metathesis involves …
The interface of metal-metal multiple bond compounds and organometallic clusters: synthesis and structure of Mo2 {. mu.-[(CO) 9Co3 (. mu. 3-CCO2)]} 4 [(CO) 9Co3 …
W Cen, P Lindenfeld, TP Fehlner - Journal of the American …, 1992 - ACS Publications
Although some related chemistry is known, 5, 8 hybrid compounds having both quadruply
bonded and trimetal alkylidyne subunits are not. Another development is the assembly of …
bonded and trimetal alkylidyne subunits are not. Another development is the assembly of …
UV photoelectron spectra and electronic structure of (η5-C5H5)(CO) 2FeB2H5. Comparison of the iron-boron bonding with the iron-carbon bonding in (CO) 4FeC2H4
RL DeKock, P Deshmukh, TP Fehlner… - Journal of the …, 1983 - ACS Publications
The electrochemical and thermodynamic properties of coprogen and ferricrocin have been
found to be similar to those of other hydroxamate siderophores. Ferricrocin, as with other …
found to be similar to those of other hydroxamate siderophores. Ferricrocin, as with other …