The state of the art of the chemistry of hypercoordinate silicon compounds is analyzed.
Published data on the current top-priority approaches to the preparative synthesis of these …

An experimental and theoretical charge density study confirms the interpretation of (cAAC)
2Si as a silylone to be valid. Two separated VSCCs present in the non‐bonding region of …

Silicon pthalocyanines (SiPcs), a class of macrocylic fused ring with 18 π-electrons system,
are emerging as a wonder class of compounds in anti-cancer treatment due to their role as …

The ωB97XD/def-TZVP method based on DFT was used to optimize the structure of C 18.
Then based on the TD-DFT ωB97XD/aug-cc-PVTZ method, the first 50 excited states were …

For the complete characterization of the molecule, quantum chemical calculations utilizing
density functional theory (DFT) were performed at the B3LYP/6–311++ G (d, p) level of …

Rational molecular design for the organic nanocrystal morphology still remains a challenge
due to the structural diversity and complicated weak intermolecular interactions. In this work …

The similarities and differences between carbon and its heavier congener silicon generate
challenging synthetic targets, especially when multiply bonded systems are concerned. The …

The electron donor–acceptor complexes, which undergo intramolecular charge transfer
under external stimulus, are an emerging class of materials showing important application in …

The development of novel synthetic methods has greatly expanded the toolbox available to
chemists for engineering porphyrin and phthalocyanine derivatives with precise electronic …

Untersuchungen der experimentell sowie theoretisch bestimmten Elektronendichte zeigen,
dass die Interpretation der Bindungssituation des (cAAC) 2Si als die eines Silylones korrekt …