Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …

Regulating nonmetallic species beyond the first coordination shell of single-atom catalysts for high-performance electrocatalysis

W Ni, H Chen, J Zeng, Y Zhang, HA Younus… - Energy & …, 2023 - pubs.rsc.org
The local microenvironment of single-atom electrocatalysts (SACs) governs their activity and
selectivity. While previous studies have focused on the first coordination shell (FCS) of metal …

Multiscale design of 3D metal–organic frameworks (M− BTC, M: Cu, Co, Ni) via PLAL enabling bifunctional electrocatalysts for robust overall water splitting

SN Shreyanka, J Theerthagiri, SJ Lee, Y Yu… - Chemical Engineering …, 2022 - Elsevier
Multiscale structural engineering of high-performance bifunctional electrocatalysts to
influence hydrogen and oxygen evolution reactions (HER and OER) has a significant role in …

Heterostructured bimetallic MOF‐on‐MOF architectures for efficient oxygen evolution reaction

Y Jiang, TY Chen, JL Chen, Y Liu, X Yuan… - Advanced …, 2024 - Wiley Online Library
Electron modulation presents a captivating approach to fabricate efficient electrocatalysts for
the oxygen evolution reaction (OER), yet it remains a challenging undertaking. In this study …

Coordinately unsaturated manganese-based metal–organic frameworks as a high-performance cathode for aqueous zinc-ion batteries

C Yin, C Pan, X Liao, Y Pan, L Yuan - ACS Applied Materials & …, 2021 - ACS Publications
The slow Zn2+ intercalation/deintercalation kinetics in cathodes severely limits the
electrochemical performance of aqueous zinc-ion batteries (ZIBs). Herein, we demonstrate a …

Recent advances in doped ruthenium oxides as high-efficiency electrocatalysts for the oxygen evolution reaction

H Sun, WC Jung - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
Rutile ruthenium oxide (RuO2) exhibits relatively high reactivity towards the oxygen
evolution reaction (OER) due to its moderate capacity to bind oxygen. Thus, RuO2 has been …

Multi-interfacial dendritic engineering facilitating congruous intrinsic activity of oxide-carbide/MOF nanostructured multimodal electrocatalyst for hydrogen and oxygen …

DR Paudel, UN Pan, RB Ghising, MR Kandel… - Applied Catalysis B …, 2023 - Elsevier
Multiple interfaces and phases between the electrode and electrolyte play a key role in
prompting the overall electrocatalysis, due to the high chances of the formation and …

Advances in MOFs and their derivatives for non‑noble metal electrocatalysts in water splitting

G Gao, X Chen, L Han, G Zhu, J Jia, A Cabot… - Coordination Chemistry …, 2024 - Elsevier
Green hydrogen is generated by water electrolysis using renewable energy sources. For
green hydrogen to become cost-effective in front of hydrogen production from fossil fuels …

Interfacial engineering-induced Janus heterostructures with enhanced electronic regulation for efficient oxygen electrocatalysis in rechargeable Zn-air batteries

J Zhang, X Dong, G Wang, J Chen, R Wang - Applied Catalysis B …, 2024 - Elsevier
Construction of efficient non-noble metal electrocatalysts for oxygen reduction reaction
(ORR) and oxygen evolution reaction (OER) are extremely important for zinc-air batteries …

CdN4C0-gra as efficient trifunctional electrocatalyst for the HER, OER and ORR: A density functional theory study

L Jin, C Liu, D Wang, M Liu, TG Lee, SG Peera… - Applied Surface …, 2023 - Elsevier
Abstract Development of a highly efficient trifunctional electrocatalyst for hydrogen evolution
reaction (HER), oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) is …