Catalytic transformation of CO 2 into C1 chemicals using hydrosilanes as a reducing agent

Y Zhang, T Zhang, S Das - Green Chemistry, 2020 - pubs.rsc.org
Utilization of CO2 for the synthesis of fine chemicals and pharmaceuticals has attracted
tremendous attention. In fact, reductive transformation of CO2 is also an interesting …

From CO 2 activation to catalytic reduction: a metal-free approach

P Sreejyothi, SK Mandal - Chemical Science, 2020 - pubs.rsc.org
Over exploitation of natural resources and human activities are relentlessly fueling the
emission of CO2 in the atmosphere. Accordingly, continuous efforts are required to find …

Betaine Catalysis for Hierarchical Reduction of CO2 with Amines and Hydrosilane To Form Formamides, Aminals, and Methylamines

XF Liu, XY Li, C Qiao, HC Fu… - Angewandte Chemie …, 2017 - Wiley Online Library
An efficient, sustainable organocatalyst, glycine betaine, was developed for the reductive
functionalization of CO2 with amines and diphenylsilane. Methylamines and formamides …

Advancements and challenges in reductive conversion of carbon dioxide via thermo-/photocatalysis

LQ Qiu, X Yao, YK Zhang, HR Li… - The Journal of Organic …, 2022 - ACS Publications
Carbon dioxide (CO2) is the major greenhouse gas and also an abundant and renewable
carbon resource. Therefore, its chemical conversion and utilization are of great attraction for …

Catalytic Reductive N‐Alkylations Using CO2 and Carboxylic Acid Derivatives: Recent Progress and Developments

JR Cabrero‐Antonino, R Adam… - Angewandte Chemie …, 2019 - Wiley Online Library
N‐Alkylamines are key intermediates in the synthesis of fine chemicals, dyes, and natural
products, and hence are highly valuable building blocks in organic chemistry. Consequently …

N-Methylation of Amines with Methanol in the Presence of Carbonate Salt Catalyzed by a Metal–Ligand Bifunctional Ruthenium Catalyst [(p-cymene) Ru (2, 2′-bpyO) …

P Liu, NT Tung, X Xu, J Yang, F Li - The Journal of Organic …, 2021 - ACS Publications
A ruthenium complex [(p-cymene) Ru (2, 2′-bpyO)(H2O)] was found to be a general and
efficient catalyst for the N-methylation of amines with methanol in the presence of carbonate …

Homogeneous Catalytic Reduction of CO2 with Silicon‐Hydrides, State of the Art

FJ Fernández‐Alvarez, LA Oro - ChemCatChem, 2018 - Wiley Online Library
During recent years, the catalytic transformation of CO2 using silicon‐hydrides as reductants
has emerged as a promising methodology that allows the selective reduction of CO2 to the …

Function-oriented ionic polymers having high-density active sites for sustainable carbon dioxide conversion

Y Chen, R Luo, J Bao, Q Xu, J Jiang… - Journal of Materials …, 2018 - pubs.rsc.org
On the basis of the development of function-oriented synthesis (FOS), we presented for the
first time an efficient and one-pot construction of functional ionic polymers (FIPs) through the …

Bifunctional aluminum catalysts for the chemical fixation of carbon dioxide into cyclic carbonates

F de la Cruz-Martínez, J Martínez… - ACS Sustainable …, 2018 - ACS Publications
Bifunctional aluminum complexes supported by novel zwitterionic NNO-donor scorpionate
ligands were found to be efficient bifunctional catalysts for cyclic carbonate synthesis from …

Selective N-formylation/N-methylation of amines and N-formylation of amides and carbamates with carbon dioxide and hydrosilanes: promotion of the basic counter …

Q Zhang, XT Lin, N Fukaya, T Fujitani, K Sato… - Green …, 2020 - pubs.rsc.org
A catalyst composed of commercially available Zn (OAc) 2 and 1, 10-phenanthroline (phen)
was effective in the N-formylation/N-methylation of amines using CO2 as the C1 source in …