Transition metal hydroxides (M‐OH) and their heterostructures (X| M‐OH, where X can be a
metal, metal oxide, metal chalcogenide, metal phosphide, etc.) have recently emerged as …

Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Abstract 2D transition metal carbides, nitrides, and carbonitrides, known as MXenes, were
discovered in 2011 and have grown to prominence in energy storage, catalysis …

Cross-coupling platforms are traditionally built around a sequence of closed-shell steps,
such as oxidative addition, transmetalation, and reductive elimination. Herein, we describe a …

The catalytic enantioselective construction of C (sp 3)− C (sp 3) bonds remains a substantial
challenge in organic synthesis. One particularly promising approach is the use of transition …

Alcohols and carboxylic acids are among the most commercially abundant, synthetically
versatile, and operationally convenient functional groups in organic chemistry. Under visible …

Methyl groups are well understood to play a critical role in pharmaceutical molecules,
especially those bearing saturated heterocyclic cores. Accordingly, methods that install …

The functionalization of C (sp3)− H bonds streamlines chemical synthesis by allowing the
use of simple molecules and providing novel synthetic disconnections. Intensive recent …

The most fundamental concepts in chemistry are structure, energetics, reactivity and their
inter-relationships, which are indispensable for promoting chemistry into a rational science …

Transition metal hydrides play a critical role in stoichiometric and catalytic transformations.
Knowledge of free energies for cleaving metal hydride bonds enables the prediction of …